One-pot synthesis of alkyl β-D-xylobioside from xylan and alcohol by acetone powder of Aureobasidium pullulans

被引:13
|
作者
Matsumura, S [1 ]
Sakiyama, K [1 ]
Toshima, K [1 ]
机构
[1] Keio Univ, Fac Sci & Technol, Dept Appl Chem, Kohoku Ku, Yokohama, Kanagawa 223, Japan
关键词
D O I
10.1023/A:1018406508711
中图分类号
Q81 [生物工程学(生物技术)]; Q93 [微生物学];
学科分类号
071005 ; 0836 ; 090102 ; 100705 ;
摘要
Alkyl beta-D-xylobioside was prepared by the one-pot reaction of xylan and a fatty alcohol using acetone powder (acetone-dried cells) of Aureobasidium pullulans KK415 (ATCC 201145). Both the yields and reaction speed were significantly increased using the acetone powder compared to those of the cell-free culture filtrate. Using 0.066% acetone powder, 2-ethylhexyl, 1-octyl and 2-octyl beta-D-xylobiosides were produced in the yields of 118, 80 and 74 mg per g xylan, respectively, when alcohol and xylan were incubated at 65 degrees C for 16 h. On the other hand, C8 alkyl xylobioside was hardly produced by the resting cells of A. pullulans.
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页码:1249 / 1253
页数:5
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