A practical approach for regioselective mono-nitration of phenols under mild conditions

被引：3
|
作者：
Chen, Ling-Yan [1 ]
Liu, Tao [1 ]
Zhou, Xiaokun [1 ]
Sun, Zhihua [1 ]
机构：
[1] Shanghai Univ Engn Sci, Coll Chem & Chem Engn, 333 Longteng Rd, Shanghai 201620, Peoples R China
来源：
ARKIVOC | 2014年
关键词：
Nitration; regioselective; metal nitrates; phenolic compounds; HIGHLY EFFICIENT NITRATION; DILUTE NITRIC-ACID; SELECTIVE NITRATION; OXIDATION; OXYGEN; PHASE;
D O I：
10.3998/ark.5550190.p008.587
中图分类号：
O62 [有机化学];
学科分类号：
070303 ; 081704 ;
摘要：
Cu(NO3)(2)center dot 3H(2)O was demonstrated to be an efficient, regioselective and inexpensive nitrating reagent for the synthesis of mono-nitro substituted phenolic compounds. 12 examples of different phenols were examined. Good yields (67-90%) have been achieved.
引用
收藏
页码：64 / 71
页数：8
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