Rh(I)-catalyzed Addition of the ortho C-H Bond in Aryl Sulfonamides to Maleimides

被引:6
|
作者
Ohara, Nozomi [1 ]
Rej, Supriya [1 ]
Chatani, Naoto [1 ]
机构
[1] Osaka Univ, Fac Engn, Dept Appl Chem, Suita, Osaka 5650871, Japan
基金
奥地利科学基金会;
关键词
C-H Activation; Rhodium; Sulfonamides; AROMATIC AMIDES; ALKYLATION; FUNCTIONALIZATION; DERIVATIVES; ALKENES; ACIDS;
D O I
10.1246/cl.200353
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
The selective, Rh(I)-catalyzed ortho-C-H alkylation of biologically important aryl sulfonamides with maleimides with the aid of an 8-aminoquinoline directing group is reported. The reaction exhibits a good substrate scope.
引用
收藏
页码:1053 / 1057
页数:5
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