A new high-nitrogen compound [Mn(ATZ)(H2O)4]•2H2O:: Synthesis and characterization

被引：31
|
作者：
Jiao, Bao-Juan
Chen, San-Ping
Zhao, Feng-Qi
Hu, Rong-Zu
Gao, Sheng-Li [1 ]
机构：
[1] NW Univ Xian, Dept Chem, Shaanxi Key Lab Phys Inorgan Chem, Xian 710069, Peoples R China
[2] Xian Modern Chem Res Inst, Xian 710065, Shaanxi, Peoples R China
来源：
JOURNAL OF HAZARDOUS MATERIALS | 2007年 / 142卷 / 1-2期
基金：
中国国家自然科学基金;
关键词：
ATZ(2-); crystal structure; single crystal; thermal analysis;
D O I：
10.1016/j.jhazmat.2006.07.066
中图分类号：
X [环境科学、安全科学];
学科分类号：
08 ; 0830 ;
摘要：
A new high-nitrogen compound [Mn(ATZ)(H2O)(4)](.)2H(2)O (ATZ=5,5-azotetrazolate) was synthesized. Crystal structure and elemental, IR and thermal analyses were investigated in the present work. It crystallized in triclinic space group P-1 with lattice parameters a= 6.304(2) angstrom, b = 7.004(2) angstrom, c = 7.921(3) angstrom, alpha = 76.114(5)-, beta = 74.023(5)1, gamma = 69.254(4)degrees. TG-DTG and DSC measurements are employed to postulate the thermal decomposition mechanism. The thermal decomposition kinetics of the main exothermic reaction was investigated by non-isothermal method and obtained its enthalpy of decomposition and the probable kinetic mechanism. An attempt was made to incorporate the relation between thermal stability and the structure. (c) 2006 Elsevier B.V. All rights reserved.
引用
收藏
页码：550 / 554
页数：5
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