Selective conversion of glycerol to acetol over sodium-doped metal oxide catalysts

被引：92

作者：

Kinage, Anil K. ^{[1
]}

Upare, Pravin P. ^{[1
,2
]}

Kasinathan, Palraj ^{[1
,2
]}

Hwang, Young Kyu ^{[1
,2
]}

Chang, Jong-San ^{[1
,2
]}

机构：

[1] KRICT, CCME, Taejon 305600, South Korea

[2] UST, Sch Sci, Taejon 305333, South Korea

来源：

CATALYSIS COMMUNICATIONS | 2010年 / 11卷 / 07期

关键词：

Glycerol conversion; Acetol; Na loaded metal oxide catalysts; Continuous fix bed reactor; HYDROGENOLYSIS; TEMPERATURE;

D O I：

10.1016/j.catcom.2010.01.008

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

Glycerol conversion to produce 1-hydroxypropan-2-one (acetol) has been investigated over 5 wt.% Na-doped on CeO2, Al2O3, ZrO2 and Ga2O3. The observed performance demonstrates that the 5 wt.% Na-doped CeO2 is one of the best catalysts to exhibit high conversion and high selectivity for acetol formation among catalysts tested in this work. XRD patterns of Na-doped catalysts showed that no alteration of metal oxide phases was observed after sodium doping. Temperature-programmed desorption (TPD) of CO2 and NH3 show the optimum number of base and acid sites on 5 wt.% Na-doped CeO2. (C) 2010 Elsevier B.V. All rights reserved.

引用

页码：620 / 623

页数：4

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