Judd-Ofelt theory: past, present and future

被引:17
|
作者
Smentek, L [1 ]
机构
[1] Nicholas Copernicus Univ, Inst Phys, PL-87100 Torun, Poland
[2] Vanderbilt Univ, Dept Chem, Nashville, TN USA
关键词
D O I
10.1080/0026897021000046717
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
The original Judd-Ofelt theory is briefly presented in the terms of effective operators defined in the traditional form that has been used for many years for the interpretation of the f spectra of rare earths. The semi-empirical approach of the Judd-Ofelt theory that defines the one-particle parametrization scheme is modified here. The unit tensor operators that act within the orbital space are replaced by double tensor operators acting within the spin-orbital space. This extension enables one to include the impact of the relativistic effects upon the transition amplitude. At the same time it leads to a generalization of the theoretical approach to f --> f transitions, especially in the case of those that are not described by the standard scheme.
引用
收藏
页码:893 / 897
页数:5
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