The antioxidant methyl 3-(3,5-di-tert-butyl-4-hydroxyphenyl)propionate

被引：12
|
作者：
Li, Xiang [1 ,2 ]
Wang, Zhi-Gang [1 ]
Chen, Hou-He [2 ]
Liu, Sheng-Gao [1 ]
机构：
[1] Chinese Acad Sci, Ningbo Inst Mat Technol & Engn, Ningbo 315201, Zhejiang, Peoples R China
[2] Nanjing Univ Sci & Technol, Dept Chem Engn, Nanjing 210094, Jiangsu, Peoples R China
来源：
ACTA CRYSTALLOGRAPHICA SECTION C-STRUCTURAL CHEMISTRY | 2014年 / 70卷
关键词：
crystal structure; antioxidant; hindered phenol; hydrogen bonding; SODIUM 2,6-DI-TERT-BUTYLPHENOXIDES; POTASSIUM; MECHANISM; ACRYLATE; ALKYLATION; PHENOLS;
D O I：
10.1107/S2053229614021445
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
The title compound, C18H28O3, was prepared by the reaction of 2,6-di-tert-butylphenol with methyl acrylate under basic conditions using dimethyl sulfoxide as the promoter. The structure of this antioxidant indicates significant strain between the ortho tert-butyl substituents and the phenolic OH group. In spite of the steric crowding of the OH group, it participates in intermolecular hydrogen bonding with the ester carbonyl O atom.
引用
收藏
页码：1050 / +
页数：9
相关论文
共 50 条
  • [31] TETRA(3,5-DI-TERT-BUTYL-4-HYDROXYPHENYL) METALLOPHTHALOCYANINES AND THEIR FREE-RADICALS
    MILAEVA, ER
    CHECHULINA, IN
    BUNDEL, YG
    VESTNIK MOSKOVSKOGO UNIVERSITETA SERIYA 2 KHIMIYA, 1989, 30 (04): : 385 - 389
  • [32] Study of 1-(3,5-di-tert-butyl-4-hydroxyphenyl)-2-arylbenzimidazoles antioxidant activity
    T. O. Khubaeva
    I. V. Khubaeva
    Russian Journal of General Chemistry, 2013, 83 : 1703 - 1706
  • [33] Study of 1-(3,5-di-tert-butyl-4-hydroxyphenyl)-2-arylbenzimidazoles antioxidant activity
    Khubaeva, T. O.
    Khubaeva, I. V.
    RUSSIAN JOURNAL OF GENERAL CHEMISTRY, 2013, 83 (09) : 1703 - 1706
  • [34] OXIDATION OF METHYL-ESTER OF BETA-(3,5-DI-TERT-BUTYL-4-HYDROXYPHENYL)PROPIONIC ACID
    KUDINOVA, LI
    VOLODKIN, AA
    ERSHOV, VV
    BULLETIN OF THE ACADEMY OF SCIENCES OF THE USSR DIVISION OF CHEMICAL SCIENCE, 1978, 27 (12): : 2497 - 2499
  • [35] FATE OF DI-(3,5-DI-TERT-BUTYL-4-HYDROXYPHENYL)METHANE (IONOX 220) IN RAT
    WRIGHT, AS
    CROWNE, RS
    HATHWAY, DE
    BIOCHEMICAL JOURNAL, 1966, 99 (01) : 146 - &
  • [36] DESIGN OF 5-(3,5-DI-TERT-BUTYL-4-HYDROXYPHENYL)-1,3,4-THIADIAZOLES, 5-(3,5-DI-TERT-BUTYL-4-HYDROXYPHENYL)-1,3,4-OXADIAZOLES, AND 5-(3,5-DI-TERT-BUTYL-4-HYDROXYPHENYL)-1,2,4-TRIAZOLES AS ORALLY-ACTIVE, NONULCEROGENIC ANTIINFLAMMATORY AGENTS
    MULLICAN, MD
    WILSON, MW
    CONNOR, DT
    KOSTLAN, CR
    SCHRIER, DJ
    DYER, RD
    JOURNAL OF MEDICINAL CHEMISTRY, 1993, 36 (08) : 1090 - 1099
  • [37] RADICAL COPOLYMERIZATION OF A VINYL MONOMER BEARING 3,5-DI-TERT-BUTYL-4-HYDROXYPHENYL GROUP
    KATO, M
    NAKANO, Y
    JOURNAL OF POLYMER SCIENCE PART B-POLYMER LETTERS, 1972, 10 (02): : 157 - &
  • [38] 5-(3,5-DI-TERT-BUTYL-4-HYDROXYPHENYL)-1,3,4-THIADIAZOLES, 5-(3,5-DI-TERT-BUTYL-4-HYDROXYPHENYL)-1,3,4-OXADIAZOLES, AND 5-(3,5-DI-TERT-BUTYL-4-HYDROXYPHENYL)-1,2,4-TRIAZOLES AS NONULCEROGENIC ANTIINFLAMMATORY AGENTS - DISCOVERY OF CI-986
    MULLICAN, MD
    WILSON, MW
    CONNOR, DT
    KOSTLAN, CR
    SCHRIER, DJ
    DYER, R
    ABSTRACTS OF PAPERS OF THE AMERICAN CHEMICAL SOCIETY, 1992, 203 : 121 - MEDI
  • [39] Study on technological conditions of transesterification reaction of synthesis of tetrakis [3-(3,5-di-tert-butyl-4-hydroxyphenyl) propionyloxymethyl] methane
    Zhang, Ruitao
    Wang, Jingdai
    Yang, Yongrong
    Huaxue Fanying Gongcheng Yu Gongyi/Chemical Reaction Engineering and Technology, 2005, 21 (06): : 556 - 559
  • [40] SYNTHESIS AND STRUCTURE OF AMINOPHOSPHONATES CONTAINING 3,5-DI-TERT-BUTYL-4-HYDROXYPHENYL AND ACETAL GROUPS
    Vagapova, Liliya I.
    Amirova, Lyaysan R.
    Syakaev, Victor V.
    Voronina, Julia K.
    Krivolapov, Dmitry B.
    Burilov, Alexander R.
    Pudovik, Michail A.
    Sinyashin, Oleg G.
    PHOSPHORUS SULFUR AND SILICON AND THE RELATED ELEMENTS, 2015, 190 (12) : 2283 - 2290
12345