Electric field induced molecular reorientation in stilbazolium salt Langmuir-Blodgett monolayers

被引:9
|
作者
Xu, JH [1 ]
Lu, XZ [1 ]
Zhou, GP [1 ]
Zhang, ZM [1 ]
机构
[1] Fudan Univ, Dept Phys, State Key Joint Lab Mat Modificat Laser Ion & Ele, Shanghai 200433, Peoples R China
基金
中国国家自然科学基金; 中国博士后科学基金;
关键词
Langmuir-Blodgett monolayers; second harmonic generation; anisotropy; time-resolved fluorescence;
D O I
10.1016/S0040-6090(97)00367-2
中图分类号
T [工业技术];
学科分类号
08 ;
摘要
Electric field induced molecular reorientation in stilbazolium salt Langmuir-Blodgett monolayers have been investigated by using rotation-angle second harmonic generation technique. The stilbazolium salt molecules were preferentially oriented along the dipping direction and this anisotropic feature was enhanced by increasing the dipping speed. An external DC electric field (6.7 x 10(5) V/m) forced the molecules to reorient along the field direction, and caused dissociation of aggregate species, as demonstrated by the steady state and time resolved fluorescence measurements. (C) 1998 Elsevier Science S.A.
引用
收藏
页码:295 / 299
页数:5
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