Binuclear cadmium dithiophosphate crystals:: 13C, 31P, and 113Cd CP/MAS NMR studies

被引：19
|
作者：
Ivanov, AV
Antzutkin, ON
Forsling, W
Rodionova, NA
机构：
[1] Russian Acad Sci, Amur Inst Integrated Res, Amur Sci Ctr, Far E Div, Blagoveshchensk 675000, Russia
[2] Lulea Univ Technol, S-97187 Lulea, Sweden
[3] Blagoveshchensk State Pedag Univ, Blagoveshchensk, Russia
来源：
RUSSIAN JOURNAL OF COORDINATION CHEMISTRY | 2003年 / 29卷 / 05期
关键词：
D O I：
10.1023/A:1023611415080
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
Binuclear diisopropyl and dicyclohexyl dithiophosphate cadmium complexes, namely, [Cd-2{S2P(OR)(2)}(4)], were studied by high-resolution heteronuclear (C-13, P-31, and Cd-113) NMR spectroscopy in the solid state in a temperature range from 295 to 378 K. P-31 NMR signals for the terminal and bridging ligands of the complexes were differentiated. The experimental NMR spectra show P-31-Cd-111,Cd-113 and (CdP)-Cd-113-P-31 spin-spin couplings only for the terminal ligands. The chemical shift aniosotropy delta(aniso) and the asymmetry parameter eta were calculated for P-31 and Cd-113 NMR signals. It was found that the P-31 chemical shifts for the terminal and bridging dithiophosphato groups differ in anisotropy character.
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页码：301 / 306
页数：6
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