Role of Noncovalent Interactions in Vanadium Tellurite Chain Con nectivities

被引：14
|
作者：
Nourmahnad, Anahita [1 ]
Smith, Matthew D. [1 ]
Zeller, Matthias [2 ]
Ferrence, Gregory M. [3 ]
Schrier, Joshua [1 ]
Norquist, Alexander J. [1 ]
机构：
[1] Haverford Coll, Dept Chem, Haverford, PA 19041 USA
[2] Youngstown State Univ, Dept Chem, Youngstown, OH 44555 USA
[3] Illinois State Univ, Dept Chem, Normal, IL 61790 USA
来源：
INORGANIC CHEMISTRY | 2015年 / 54卷 / 02期
基金：
美国国家科学基金会;
关键词：
CENTER-DOT-O; COMPOSITION SPACE ANALYSIS; MELTING-POINT ALTERNATION; BOND-VALENCE PARAMETERS; NONCENTROSYMMETRIC MOLYBDATES; HYDROGEN-BOND; STRUCTURAL DIVERSITY; INTERACTION REGIONS; DIRECTED SYNTHESIS; ORGANIC FRAMEWORK;
D O I：
10.1021/ic502753e
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
Structural differences in [V2Te2O10](n)(2n-) chain metrics are directly ascribed to variations in noncovalent interactions in a series of organically templated vanadium tellurites, including [C6H17N3][V2Te2O10].H2O, [C5H16N2][V2Te2O10], and [C4H14N2][V2Te2O10]. The noncovalent interaction (NCI) method was used to locate, quantify, and visualize intermolecular interactions in [C4H14N2][V2Te2O10] and [C5H16N2][V2Te2O10]. Variations in the van der Waals attractions between [1,4-diaminobutaneH2](2+) and [1,5-diaminopentaneH(2)](2+) result in divergent packing motifs for these cations, which causes a reorganization of N-H...O hydrogen bonding and variances in the [V2Te2O10](n)(2n-) chain metrics. The application of the NCI method to this type of solid-state structure provides a direct method to elucidate the structural effects of weak noncovalent interactions.
引用
收藏
页码：694 / 703
页数：10
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