Synthesis and structure of the λ6Si-silicate [Cs(18-crown-6)]2[SKOSO2CH3)6]

被引：1

作者：

Georg, Isabelle ^{[1
]}

Bolte, Michael ^{[1
]}

Wagner, Matthias ^{[1
]}

Lerner, Hans-Wolfram ^{[1
]}

机构：

[1] Goethe Univ Frankfurt, Inst Anorgan Chem, Max von Laue Str 7, D-60438 Frankfurt, Germany

来源：

ZEITSCHRIFT FUR NATURFORSCHUNG SECTION B-A JOURNAL OF CHEMICAL SCIENCES | 2021年 / 76卷 / 6-7期

关键词：

cesium; hexachlorodisilane; methanesulfonate; silicate; X-ray structure analysis; PENTASILICON DODECACHLORIDE; CHEMISTRY;

D O I：

10.1515/znb-2021-0068

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The lambda Si-6-silicate [Cs(18-crown-6)](2)[Si(OSO2CH3)(6)] (1) was synthesized by treatment of Si2C16 with Cs[OSO2CH3] in the presence of 18-crown-6. Compound 1 is the first example of a lambda Si-6-silicate with a methanesulfonate ligand. It was characterized by NMR spectroscopy and by single-crystal X-ray diffraction. The solid-state structure of 1 consists of discrete [Si(OSO2CH3)(6)](2-) anions and two [Cs(18-crown-6)](+) cations (triclinic space group, P (1) over bar, Z = 1).

引用

页码：335 / 339

页数：5

共 50 条

[31] PREPARATION AND STRUCTURE OF THE 18-CROWN-6 2(CHLORAL HYDRATE) COMPLEX
CHENEVERT, R
CHAMBERLAND, D
CHEMISTRY LETTERS, 1989, (07) : 1123 - 1124
[32] Pb(18-crown-6)Cl2 and Hg(18-crown-6)I2: Molecular Dihalides Trapped in a Crown Ether
Rieger, Franziska
Mudring, Anja-Verena
ZEITSCHRIFT FUR ANORGANISCHE UND ALLGEMEINE CHEMIE, 2008, 634 (15): : 2989 - 2993
[33] Conformational Study of the Structure of dibenzo-18-crown-6. Comparison with 18-crown-6
Al-Jallal, Nada A.
El-Azhary, Adel. A.
JOURNAL OF MOLECULAR GRAPHICS & MODELLING, 2017, 75 : 49 - 54
[34] SYNTHESIS AND CRYSTAL-STRUCTURE OF [SC(NO3)3(OH2)3]. (18-CROWN-6)
JIN, ZS
LIU, YS
ZHANG, SG
YU, FL
NI, JZ
ACTA CHIMICA SINICA, 1987, 45 (11) : 1048 - 1052
[35] SYNTHESIS AND X-RAY CRYSTAL-STRUCTURE OF A MONONUCLEAR ARYLOXIDE-CROWN ETHER OF BARIUM - [BA(OAR)2(18-CROWN-6)].(2AROH)(18-CROWN-6) (AR = C6H3BUT2-3,5)
MIELE, P
FOULON, JD
HOVNANIAN, N
COT, L
POLYHEDRON, 1993, 12 (03) : 267 - 271
[36] SYNTHESIS AND CRYSTAL-STRUCTURES OF THE IONIC CROWN-ETHER COMPLEXES [TICL3(15-CROWN-5)(CH3CN)][SBCL6] AND [VCL(OH)(18-CROWN-6)(CH3CN)2][SBCL6].1/2(18-CROWN-6.CH3CN)
PLATE, M
FRENZEN, G
DEHNICKE, K
ZEITSCHRIFT FUR NATURFORSCHUNG SECTION B-A JOURNAL OF CHEMICAL SCIENCES, 1993, 48 (02): : 149 - 155
[37] Synthesis and Crystal Structure of [K（18-Crown-6）]3P11·2en
戴枫荣
徐立
Chinese Journal of Structural Chemistry, 2007, (01) : 45 - 48
[38] Synthesis and Crystal Structure of Hexakis(isothiocyanato)erbium(III) Thiocyanate Bis(18-Crown-6)dipotassium Bis[(18-Crown-6)ethanolpotassium]
Chekhlov, A. N.
RUSSIAN JOURNAL OF COORDINATION CHEMISTRY, 2008, 34 (11) : 849 - 854
[39] Synthesis and crystal structure of [K(18-crown-6)]3P11•2en
Dai Feng-Rong
Xu Li
CHINESE JOURNAL OF STRUCTURAL CHEMISTRY, 2007, 26 (01) : 45 - 48
[40] Synthesis and crystal structure of hexakis(isothiocyanato)erbium(III) thiocyanate bis(18-crown-6)dipotassium bis[(18-crown-6)ethanolpotassium]
A. N. Chekhlov
Russian Journal of Coordination Chemistry, 2008, 34 : 849 - 854

← 1 2 3 4 5 →