The occupied and unoccupied electronic structure of adsorbed ferrocene

被引:29
|
作者
Dowben, PA [1 ]
Waldfried, C
Komesu, T
Welipitiya, D
McAvoy, T
Vescovo, E
机构
[1] Univ Nebraska, Behlen Lab Phys, Dept Phys & Astron, Lincoln, NE 68588 USA
[2] Univ Nebraska, Ctr Mat Res & Anal, Lincoln, NE 68588 USA
[3] Brookhaven Natl Lab, Natl Synchrotron Light Source, Upton, NY 11973 USA
关键词
D O I
10.1016/S0009-2614(97)01316-X
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
We have studied both the occupied and unoccupied molecular orbitals of adsorbed ferrocene. The occupied molecular orbitals have been identified using a combination of photoemission selection rules and resonant photoemission. Ferrocene adsorbs with a strong preferential molecular orientation on Mo(112) at 150 K, like metallocenes on many other surfaces. Though the ferrocene molecular axis is largely parallel with the Mo(112) surface there is very little perturbation of the molecular orbitals relative to the gas phase. (C) 1998 Elsevier Science B.V.
引用
收藏
页码:44 / 50
页数:7
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