Facile one-pot synthesis of nanoporous hypercrosslinked hydroxybenzene formaldehyde resins with high surface area and adjustable pore texture

被引：10

作者：

Zeng, Shao-Zhong ^{[1
]}

Guo, Limin ^{[1
]}

He, Qianjun ^{[1
]}

Chen, Yu ^{[1
]}

Jiang, Peng ^{[1
]}

Shi, Jianlin ^{[1
]}

机构：

[1] Chinese Acad Sci, Shanghai Inst Ceram, State Key Lab High Performance Ceram & Superfine, Shanghai 200050, Peoples R China

来源：

MICROPOROUS AND MESOPOROUS MATERIALS | 2010年 / 131卷 / 1-3期

关键词：

Hydroxybenzene; Hypercrosslinked; Nanostructure; Polymers; Synthetic methods; COVALENT ORGANIC FRAMEWORKS; INTRINSIC MICROPOROSITY PIMS; HYDROGEN STORAGE; POLYMERS; CRYSTALLINE; ADSORPTION; COPOLYMER; NETWORKS;

D O I：

10.1016/j.micromeso.2009.12.014

中图分类号：

O69 [应用化学];

学科分类号：

081704 ;

摘要：

Hydroxybenzene formaldehyde resins with high surface area (up to 1000 m(2) g(-1)), high pore volume (up to 2.4 cm(3) g(-1)) and adjustable pore size distribution have been synthesized by a facile one-pot method. The pore formation was confirmed to be a hypercrosslinked mechanism. These results extend the synthetic methods of hypercrosslinked polymers from conventional nonaqueous Friedel-Crafts condensation to aqueous phenol-aldehyde reaction. (C) 2009 Elsevier Inc. All rights reserved.

引用

页码：141 / 147

页数：7

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