Ligandless Palladium-Catalyzed Reductive Carbonylation of Aryl Iodides under Ambient Conditions

被引：16
|
作者：
Han, Wei [1 ,2 ]
Liu, Binbin [1 ]
Chen, Junjie [1 ]
Zhou, Qing [1 ]
机构：
[1] Nanjing Normal Univ, Sch Chem & Mat Sci, Key Lab Appl Photochem, Jiangsu Key Lab Biofunct Mat, Wenyuan Rd 1, Nanjing 210023, Jiangsu, Peoples R China
[2] Jiangsu Collaborat Innovat Ctr Biomed Funct Mat, Nanjing 210023, Jiangsu, Peoples R China
来源：
SYNLETT | 2017年 / 28卷 / 07期
关键词：
aromatic aldehydes; aryl iodides; reductive carbonylation; ligandless; ambient conditions; SUZUKI COUPLING REACTION; IN-SITU GENERATION; ARYLBORONIC ACIDS; FORMYLATION; NANOPARTICLES; HALIDES; EFFICIENT; PRESSURE; BROMIDES; ALDEHYDES;
D O I：
10.1055/s-0036-1588930
中图分类号：
O62 [有机化学];
学科分类号：
070303 ; 081704 ;
摘要：
Ligandless palladium-catalyzed reductive carbonylation of aryl iodides for the synthesis of aromatic aldehydes has been developed. This carbonylation process proceeded effectively even under ambient temperature and pressure. In addition, this method enables successive reductive carbonylation of diiodobenzenes to furnish dialdehydes in satisfactory yields. Finally, the nature of the active catalytic species is discussed.
引用
收藏
页码：835 / 840
页数：6
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