Molecular Oligogermanes and Related Compounds: Structure, Optical and Semiconductor Properties

被引:24
|
作者
Zaitsev, Kirill V. [1 ]
Tafeenko, Viktor A. [1 ]
Oprunenko, Yuri F. [1 ]
Kharcheva, Anastasia V. [1 ]
Zhanabil, Zhaisan [2 ]
Suleimen, Yerlan [2 ]
Lam, Kevin [2 ]
Zaitsev, Vladimir B. [3 ]
Zaitseva, Anna V. [4 ]
Zaitseva, Galina S. [1 ]
Karlov, Sergey S. [1 ]
机构
[1] Moscow MV Lomonosov State Univ, Dept Chem, Leninskye Gory 1,3, Moscow 3119991, Russia
[2] Nazarbayev Univ, Dept Chem, Sch Sci & Technol, Astana 010000, Kazakhstan
[3] Moscow MV Lomonosov State Univ, Dept Phys, Leninskye Gory 1, Moscow 1119991, Russia
[4] Russian Acad Sci, Inst Phys Chem, Leninskii Pr 31, Moscow, Russia
关键词
luminescence; oligogermanes; organic semiconductors; silagermanes; X-ray analysis; HEXA-TERT-BUTYLCYCLOTRIGERMANE; POLYSILANE HIGH POLYMERS; BRANCHED OLIGOGERMANES; ELECTRONIC TRANSPORT; POLYGERMANES; GERMANIUM; GE; SI; ELECTROCHEMISTRY; CRYSTALLIZATION;
D O I
10.1002/asia.201700151
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
The optical (UV/Vis absorbance, fluorescence in the solid state and in solution) and semiconducting properties of a number of di- and trigermanes as well as related silicon- and tin-containing germanes, 1-6 ((p-Tol)(3)GeGeMe3 (1), Ph3SnGe(SiMe3)(3) (2), (C6F5)(3)GeGePh3 (3), (p-Tol)(3)GeSiMe2SiMe3 (4), (p-Tol)(3)GeGeMe2Ge(p-Tol)(3) (5), (p-Tol)(3)GeSiMe2SiMe2Ge(p-Tol)(3) (6)) were investigated. Molecular structures of 5 and 6 were studied by X-ray diffraction analysis. All compounds displayed luminescence properties. In addition, a band gap (of about 3.3eV) was measured for compounds1-6 showing that those molecules display semiconductor properties.
引用
收藏
页码:1240 / 1249
页数:10
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