Molecular Oligogermanes and Related Compounds: Structure, Optical and Semiconductor Properties

被引：24

作者：

Zaitsev, Kirill V. ^{[1
]}

Tafeenko, Viktor A. ^{[1
]}

Oprunenko, Yuri F. ^{[1
]}

Kharcheva, Anastasia V. ^{[1
]}

Zhanabil, Zhaisan ^{[2
]}

Suleimen, Yerlan ^{[2
]}

Lam, Kevin ^{[2
]}

Zaitsev, Vladimir B. ^{[3
]}

Zaitseva, Anna V. ^{[4
]}

Zaitseva, Galina S. ^{[1
]}

Karlov, Sergey S. ^{[1
]}

机构：

[1] Moscow MV Lomonosov State Univ, Dept Chem, Leninskye Gory 1,3, Moscow 3119991, Russia

[2] Nazarbayev Univ, Dept Chem, Sch Sci & Technol, Astana 010000, Kazakhstan

[3] Moscow MV Lomonosov State Univ, Dept Phys, Leninskye Gory 1, Moscow 1119991, Russia

[4] Russian Acad Sci, Inst Phys Chem, Leninskii Pr 31, Moscow, Russia

来源：

CHEMISTRY-AN ASIAN JOURNAL | 2017年 / 12卷 / 11期

关键词：

luminescence; oligogermanes; organic semiconductors; silagermanes; X-ray analysis; HEXA-TERT-BUTYLCYCLOTRIGERMANE; POLYSILANE HIGH POLYMERS; BRANCHED OLIGOGERMANES; ELECTRONIC TRANSPORT; POLYGERMANES; GERMANIUM; GE; SI; ELECTROCHEMISTRY; CRYSTALLIZATION;

D O I：

10.1002/asia.201700151

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The optical (UV/Vis absorbance, fluorescence in the solid state and in solution) and semiconducting properties of a number of di- and trigermanes as well as related silicon- and tin-containing germanes, 1-6 ((p-Tol)(3)GeGeMe3 (1), Ph3SnGe(SiMe3)(3) (2), (C6F5)(3)GeGePh3 (3), (p-Tol)(3)GeSiMe2SiMe3 (4), (p-Tol)(3)GeGeMe2Ge(p-Tol)(3) (5), (p-Tol)(3)GeSiMe2SiMe2Ge(p-Tol)(3) (6)) were investigated. Molecular structures of 5 and 6 were studied by X-ray diffraction analysis. All compounds displayed luminescence properties. In addition, a band gap (of about 3.3eV) was measured for compounds1-6 showing that those molecules display semiconductor properties.

引用

页码：1240 / 1249

页数：10

共 50 条

[1] MOLECULAR STRUCTURE AND PROPERTIES OF HYDROCARBONS AND RELATED COMPOUNDS
GREENSHIELDS, JB
ROSSINI, FD
JOURNAL OF PHYSICAL CHEMISTRY, 1958, 62 (03): : 271 - 280
[2] RELATIONSHIP OF MOLECULAR STRUCTURE TO NONLINEAR OPTICAL PROPERTIES OF ORGANIC HETEROCYCLIC COMPOUNDS
Hu, Ying
Danilov, Evgeny O.
Wex, Brigitte
Neckers, Douglas C.
JOURNAL OF NONLINEAR OPTICAL PHYSICS & MATERIALS, 2008, 17 (03) : 275 - 283
[3] The molecular structure of the tungstosilicates and related compounds
Pauling, L
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1929, 51 : 2868 - 2880
[4] Optical properties of A(II)B(V) semiconductor compounds
Mudryi, AV
Patuk, AI
Shakin, IA
Kalmykov, AE
Marenkin, SF
Raukhman, AM
MATERIALS CHEMISTRY AND PHYSICS, 1996, 44 (02) : 151 - 155
[5] MESOMORPHIC PROPERTIES AND MOLECULAR-STRUCTURE OF 4 CLOSELY RELATED-COMPOUNDS
MITRA, M
PAUL, R
PAUL, S
MOLECULAR CRYSTALS AND LIQUID CRYSTALS, 1989, 177 : 71 - 80
[6] A study of the molecular structure and spectroscopic properties of tetrahydro[4]beltene and related compounds
Galasso, V
Grimme, W
Lex, J
Jones, D
Modelli, A
CHEMICAL PHYSICS, 1999, 242 (02) : 203 - 216
[7] "Donor-Acceptor" Oligogermanes: Synthesis, Structure, and Electronic Properties
Zaitsev, Kirill V.
Kapranov, Andrey A.
Churakov, Andrei V.
Poleshchuk, Oleg Kh.
Oprunenko, Yuri F.
Tarasevich, Boris N.
Zaitseva, Galina S.
Karlov, Sergey S.
ORGANOMETALLICS, 2013, 32 (21) : 6500 - 6510
[8] Donor-acceptor molecular oligogermanes: Novel properties and structural aspects
Zaitsev, Kirill V.
Kharcheva, Anastasia V.
Lam, Kevin
Zhanabil, Zhaisan
Issabayeva, Guldana
Oprunenko, Yuri F.
Churakov, Andrei V.
Zaitseva, Galina S.
Karlov, Sergey S.
JOURNAL OF ORGANOMETALLIC CHEMISTRY, 2018, 867 : 228 - 237
[9] Nonlinear optical properties of phthalocyanines and related compounds
Diaz-Garcia, Maria A.
JOURNAL OF PORPHYRINS AND PHTHALOCYANINES, 2009, 13 (4-5) : 652 - 667
[10] Optical properties of molecular layer of pyrylium compounds
Kaliteevskaya, Elena
Krutyakova, Valentina
Razumova, Tatiana
Starovoytov, Anton
OPTICAL AND QUANTUM ELECTRONICS, 2020, 52 (02)

← 1 2 3 4 5 →