Synthesis and structure of [{Sb(NCy)3}{Cd[N(SiMe3)2]}3]•[Li{N(SiMe3)2}•thf]2, containing a bimetallic [SbCd3] cage

被引：10
|
作者：
Bashall, A
Beswick, MA
Harmer, CN
McPartlin, M
Paver, MA
Wright, DS
机构：
[1] Univ Cambridge, Dept Chem, Cambridge CB2 1EW, England
[2] Univ N London, Sch Appl Chem, London N7 8DB, England
来源：
JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS | 1998年 / 04期
关键词：
D O I：
10.1039/a707816a
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
The reaction of [{Sb(NCy)(3)}(2)Li-6] with [Cd{N(SiMe3)(2)}(2)] (1:6 equivalents) gave the unusual co-complex [{Sb(NCy)(3)}{Cd[N(SiMe3)(2)]}(3)].[Li{N(SiMe3)(2)}. thf](2), containing a heterobimetallic [SbCd3] cage.
引用
收藏
页码：517 / 518
页数：2
相关论文
共 50 条
  • [31] CRYSTAL-STRUCTURE OF N-LITHIOHEXAMETHYLDISILAZANE, [LIN(SIME3)2]3
    ROGERS, RD
    ATWOOD, JL
    GRUNING, R
    [J]. JOURNAL OF ORGANOMETALLIC CHEMISTRY, 1978, 157 (02) : 229 - 237
  • [32] Crystal structure of the zinc amide Zn[N(SiMe3)2]2
    Margraf, G
    Lerner, HW
    Bolte, M
    Wagner, M
    [J]. ZEITSCHRIFT FUR ANORGANISCHE UND ALLGEMEINE CHEMIE, 2004, 630 (02): : 217 - 218
  • [33] Synthesis and reactivity of the bulky germanium(IV) trisamide complexes BrGe[N(SiMe3)2]3 and LiGe[N(SiMe3)2]3:: X-ray crystal structures of BrGe[N(SiMe3)2]3 and [(Me3Si)2N]3Ge(CH2CH2CH2CH3)
    Walding, JL
    Fanwick, PE
    Weinert, CS
    [J]. INORGANICA CHIMICA ACTA, 2005, 358 (04) : 1186 - 1192
  • [34] THE ISO-TETRAPHOSPHANE P[P(SIME3)ME]2[P(SIME3)2]
    FRITZ, G
    STOLL, K
    MATERN, E
    [J]. ZEITSCHRIFT FUR ANORGANISCHE UND ALLGEMEINE CHEMIE, 1990, 586 (07): : 41 - 46
  • [35] ELECTRON-SPIN RESONANCE OF T-ALKYL-AMINYL, SILYL-AMINYL AND GERMYL-AMINYL RADICALS AND SOME OBSERVATIONS ON THE AMIDES GEBR(N(SIME3)2)3, 5NBR(N(SIME3)2)3, PBBR(N(SIME3)2)3
    GUMRUKCU, I
    HUDSON, A
    LAPPERT, MF
    SLADE, MJ
    POWER, PP
    [J]. JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS, 1980, (16) : 776 - 777
  • [36] Synthesis and structures of the [benzamidinato]3- complexes Li3(tmeda)(L1)]2 and [Li(thf)4][Li5(L2)(OEt2)2] [L1 = N(SiMe3)C(Ph)N(SiMe3) and L2 = N(SiMe3) C(C6H4-4) NPh]
    Coles, Martyn P.
    Hitchcock, Peter B.
    Khvostov, Alexei V.
    Lappert, Michael F.
    Maron, Laurent
    [J]. DALTON TRANSACTIONS, 2011, 40 (12) : 3047 - 3052
  • [37] SYNTHESIS, PHOTOCHEMISTRY AND X-RAY CRYSTAL-STRUCTURES OF THE METHYLTRIS[BIS(TRIMETHYLSILYL)AMIDO] COMPOUNDS METI[N(SIME3)2]3 AND MEZR[N(SIME3)2]3
    BRADLEY, DC
    CHUDZYNSKA, H
    BACKERDIRKS, JDJ
    HURSTHOUSE, MB
    IBRAHIM, AA
    MOTEVALLI, M
    SULLIVAN, AC
    [J]. POLYHEDRON, 1990, 9 (11) : 1423 - 1427
  • [38] Disproportionation of Sn(ii){CH(SiMe3)2}2 to Sn(iii){CH(SiMe3)2}3 and Sn(i){CH(SiMe3)2}: characterization of the Sn(i) product
    Mears, Kristian L.
    Ruiz, Bronson
    Nguyen, Gia-Ann
    Zou, Wenxing
    Fettinger, James C.
    Power, Philip P.
    [J]. CHEMICAL COMMUNICATIONS, 2023, 59 (42) : 6399 - 6402
  • [39] N-substituted guanidinate anions as ancillary ligands in group 4 chemistry.: Syntheses and characterization of M{RNC[N(SiMe3)2]NR}2Cl2, [M{CyNC[N(SiMe3)2]NCy}Cl3]- (M = zr, hf; R = iPr, cy), and Zr{CyNC[N(SiMe3)2]NCy}(CH2Ph)3
    Wood, D
    Yap, GPA
    Richeson, DS
    [J]. INORGANIC CHEMISTRY, 1999, 38 (25) : 5788 - 5794
  • [40] In situ Crystallization of N(SiMe3)3 and As(SiMe3)3: Trigonal planar or pyramidal coordination of the central atoms?
    Merz, Klaus
    Bieda, Ruth
    [J]. ZEITSCHRIFT FUR KRISTALLOGRAPHIE-CRYSTALLINE MATERIALS, 2014, 229 (09): : 635 - 638
12345