Low temperature NH3-SCR reaction over MnOx supported on protonated titanate

被引:19
|
作者
Wang, Tianyou [1 ]
Sun, Kai [1 ]
Lu, Zhen [1 ]
Zhang, Yajun [1 ]
机构
[1] Tianjin Univ, State Key Lab Engines, Tianjin 300072, Peoples R China
关键词
Low temperature NH3-SCR; MnOx; Protonated titanate; SELECTIVE CATALYTIC-REDUCTION; NITRIC-OXIDE; AMMONIA; NO; NANOTUBES; NH3;
D O I
10.1007/s11144-010-0209-8
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
In the present work, protonated titanate nanoribbons were prepared by hydrothermal treating of TiO2 in alkali solution, followed by a thorough acid washing. The protonated titanate nanoribbons were employed as novel support for MnOx species and MnOx/protonated titanate was studied as a promising catalyst for the low temperature NH3-SCR reaction. The maximal NO conversion of ca. 98% was achieved over MnOx/protonated titanate at 200 A degrees C under high GHSV of 50000 h(-1). The existence of both MnO2 and Mn2O3 as active Mn species on protonated titanate was confirmed by XPS analysis, which was responsible for the high deNO(x) activity of MnOx/protonated titanate in NH3-SCR reaction.
引用
收藏
页码:153 / 161
页数:9
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