Standard Gibbs energies of transfer of halogenate and pseudohalogenate ions, halogen substituted acetates, and cycloalkyl carboxylate anions at the water\nitrobenzene interface

被引：42

作者：

Gulaboski, R ^{[1
]}

Riedl, K ^{[1
]}

Scholz, F ^{[1
]}

机构：

[1] Ernst Moritz Arndt Univ Greifswald, Inst Chem & Biochem, D-17489 Greifswald, Germany

来源：

PHYSICAL CHEMISTRY CHEMICAL PHYSICS | 2003年 / 5卷 / 06期

关键词：

D O I：

10.1039/b210356g

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

The previously introduced three-phase electrode technique was used to determine the Gibbs energies of transfer of ClO3-, BrO3-, IO3-, IO4-, OCN-, SeCN-, CN-, N-3(-), halogen substituted acetate anions Z(3-n)CH(n)COO(-) (Z = F,Cl,Br,I), and cycloalkyl carboxylate anions ((CH2)(n)COO-, n = 3,...,7) at the water\nitrobenzene interface. Whereas the data for the small inorganic ions can easily be understood in terms of ion-dipole interactions, the data of the organic ions need consideration of charge delocalisation and its effect on the enthalpy and entropy of solvation.

引用

页码：1284 / 1289

页数：6

共 22 条

[1] STANDARD GIBBS ENERGIES OF TRANSFER OF IONS ACROSS THE WATER CHLOROBENZENE + NITROBENZENE INTERFACE
SOLOMON, T
ALEMU, H
HUNDHAMMER, B
[J]. JOURNAL OF ELECTROANALYTICAL CHEMISTRY, 1984, 169 (1-2): : 311 - 314
[2] Determination of standard Gibbs energies of transfer of organic anions across the water/nitrobenzene interface
Komorsky-Lovric, S
Riedl, K
Gulaboski, R
Mirceski, V
Scholz, F
[J]. LANGMUIR, 2002, 18 (21) : 8000 - 8005
[3] Determination of the standard Gibbs energies of transfer of cations and anions of amino acids and small peptides across the water nitrobenzene interface
Gulaboski, R
Mirceski, V
Scholz, F
[J]. AMINO ACIDS, 2003, 24 (1-2) : 149 - 154
[4] Determination of the standard Gibbs energies of transfer of cations and anions of amino acids and small peptides across the water nitrobenzene interface
R. Gulaboski
V. Mirčeski
F. Scholz
[J]. Amino Acids, 2003, 24 : 149 - 154
[5] STANDARD GIBBS ENERGIES OF TRANSFER OF IONS ACROSS THE WATER ACETOPHENONE INTERFACE
SOLOMON, T
ALEMU, H
HUNDHAMMER, B
[J]. JOURNAL OF ELECTROANALYTICAL CHEMISTRY, 1984, 169 (1-2): : 303 - 309
[6] Determination of standard Gibbs energies of transfer of organic anions across the water/nitrobenzene interface (vol 18, pg 8000, 2002)
Komorsky-Lovric, S
Riedl, K
Gulaboski, R
Mirceski, V
Scholz, F
[J]. LANGMUIR, 2003, 19 (07) : 3090 - 3090
[7] Determination of the standard Gibbs energies of transfer of cations across the nitrobenzene|water interface utilizing the reduction of iodine in an immobilized nitrobenzene droplet
Mirceski, V
Gulaboski, R
Scholz, F
[J]. ELECTROCHEMISTRY COMMUNICATIONS, 2002, 4 (10) : 814 - 819
[8] The determination of standard Gibbs energies of transfer of cations across the nitrobenzene|water interface using a three-phase electrode
Scholz, F
Gulaboski, R
Caban, K
[J]. ELECTROCHEMISTRY COMMUNICATIONS, 2003, 5 (11) : 929 - 934
[9] Standard Gibbs free energies for transfer of actinyl ions at the aqueous/organic solution interface
Kitatsuji, Yoshihiro
Okugaki, Tomohiko
Kasuno, Megumi
Kubota, Hiroki
Maeda, Kohji
Kimura, Takaumi
Yoshida, Zenko
Kihara, Sorin
[J]. JOURNAL OF CHEMICAL THERMODYNAMICS, 2011, 43 (06): : 844 - 851
[10] STANDARD GIBBS ENERGIES OF TRANSFER OF UNIVALENT IONS FROM WATER TO 1,2-DICHLOROETHANE
SABELA, A
MARECEK, V
SAMEC, Z
FUOCO, R
[J]. ELECTROCHIMICA ACTA, 1992, 37 (02) : 231 - 235

← 1 2 3 →