Synthesis of Unnatural Arundines Using a Magnetically Reusable Copper Ferrite Catalyst

被引：13

作者：

Ha, Pha T. ^{[1
]}

Nguyen, Oanh T. K. ^{[1
]}

Huynh, Khoa D. ^{[1
]}

Nguyen, Tung T. ^{[1
]}

Phan, Nam T. S. ^{[1
]}

机构：

[1] HCMC Univ Technol, VNU HCM, Fac Chem Engn, 268 Ly Thuong Kiet,Dist 10, Ho Chi Minh City, Vietnam

来源：

SYNLETT | 2018年 / 29卷 / 15期

关键词：

copper ferrite; C-H functionalization; indoles; Arundine; dimerization; C-H BONDS; LIGAND-FREE CONDITIONS; ONE-POT SYNTHESIS; CUFE2O4; NANOPARTICLES; METHYLENATING REAGENT; ARYLATION; INDOLES; CUO; BIS; FUNCTIONALIZATION;

D O I：

10.1055/s-0037-1610227

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

We report a method for copper ferrite-catalyzed coupling of indoles and N,N-dimethylacetamide (DMA) to afford Arundine derivatives. Halogen, methoxy, boronate ester, and trimethylsilyl functionalities are compatible with reaction conditions. Unprotected or sterically hindered indoles are also competent substrates. Indoles containing competitively reactive pyrazoles deliver the desired products in reasonable yields. The copper ferrite is easily recovered and reused, up to nine times without a significant yield loss.

引用

页码：2031 / 2034

页数：4

共 50 条

[41] A Novel and Efficient Magnetically Recoverable Copper Catalyst for Synthesis of Symmetrical Diaryl Selenides and Sulfides
Sadeq, Alshimaysawee
Hasan, Yaser Mohamed
Najm, Zainab Mohsen
Kadhim, Mustafa M. M.
Al Mashhadani, Zuhair I. I.
POLYCYCLIC AROMATIC COMPOUNDS, 2023,
[42] Greener synthesis of 1,2,3-triazoles using a copper(i)-exchanged magnetically recoverable β-zeolite as catalyst
Costa, Elizama R.
Andrade, Floyd C. D.
de Albuquerque, Danilo Yano
Ferreira, Luanne E. M.
Lima, Thiago M.
Lima, Carolina G. S.
Silva, Domingos S. A.
Urquieta-Gonzalez, Ernesto A.
Paixao, Marcio W.
Schwab, Ricardo S.
NEW JOURNAL OF CHEMISTRY, 2020, 44 (35) : 15046 - 15053
[43] Nickel(0) nanoparticles supported on bare or coated cobalt ferrite as highly active, magnetically isolable and reusable catalyst for hydrolytic dehydrogenation of ammonia borane
Manna, Joydev
Akbayrak, Serdar
Ozkar, Saim
JOURNAL OF COLLOID AND INTERFACE SCIENCE, 2017, 508 : 359 - 368
[44] Assemblies of Copper Ferrite and Palladium Nanoparticles on Silica Microparticles as a Magnetically Recoverable Catalyst for Sonogashira Reaction under Mild Conditions
Gholinejad, Mohammad
Ahmadi, Jahantab
CHEMPLUSCHEM, 2015, 80 (06): : 973 - 979
[45] A copper-free Sonogashira reaction using nickel ferrite as catalyst in water
Moghaddam, Firouz Matloubi
Tavakoli, Ghazal
Rezvani, Hamid Reza
CATALYSIS COMMUNICATIONS, 2015, 60 : 82 - 87
[46] Silver complex anchored on ordered mesoporous coated cobalt ferrite nanoparticles as highly reusable catalyst for synthesis of tetrazole
Molaei, Somayeh
Ghadermazi, Mohammad
APPLIED SURFACE SCIENCE ADVANCES, 2023, 18
[47] One-pot, three-component synthesis of pyrimidine heterocyclic derivatives using reusable zinc ferrite catalyst and molecular docking study
Divya, J.
Gayathri, P.
Muthuvel, I
Thirunarayanan, G.
INDIAN JOURNAL OF CHEMISTRY, 2023, 62 (11): : 1178 - 1185
[48] Magnetically Reusable Polymetallic Pd-Catalyst for Sonogashira Reaction in Ionic Liquid
Bumagin, N. A.
RUSSIAN JOURNAL OF GENERAL CHEMISTRY, 2023, 93 (02) : 332 - 344
[49] Green Synthesis Using Tragacanth Gum and Characterization of Ni-Cu-Zn Ferrite Nanoparticles as a Magnetically Separable Catalyst for the Synthesis of Hexabenzylhexaazaisowurtzitane Under Ultrasonic Irradiation
Fardood, S. Taghavi
Ramazani, A.
Golfar, Z.
Joo, S. W.
JOURNAL OF STRUCTURAL CHEMISTRY, 2018, 59 (07) : 1730 - 1736
[50] Synthesis of Copper Ferrite Nanoparticles
Kuznetsov, M. V.
Morozov, Yu G.
Belousova, O. V.
INORGANIC MATERIALS, 2013, 49 (06) : 606 - 615

← 1 2 3 4 5 →