Multipolymers with Fischer-Tropsch olefins

被引:10
|
作者
Tincul, I [1 ]
Smith, J [1 ]
van Zyl, P [1 ]
机构
[1] Sasol Technol R&D, ZA-1947 Sasolburg, South Africa
关键词
D O I
10.1002/masy.200390047
中图分类号
O63 [高分子化学(高聚物)];
学科分类号
070305 ; 080501 ; 081704 ;
摘要
Multipolymers consisting of ethylene, 1-heptene, 3-methylpentene and 4-methylpentene were prepared with a heterogeneous Ziegler-Natta catalyst. The polymers were prepared in such a way that the molar fraction of the comonomers remained the same. Copolymers of ethylene/1-heptene and ethylene/4-methylpentene were prepared in order to study the changes in polymer characteristics as one moves from an ethylene/linear alpha olefin copolymer through ethylene multipolymers to an ethylene/4-methylpentene copolymer. The mechanical, rheological and application properties showed expected trends.
引用
收藏
页码:13 / 28
页数:16
相关论文
共 50 条
  • [21] Iron foam catalysts for forming olefins via Fischer-Tropsch synthesis
    Ali, Basit
    Huang, Jielang
    Zhang, Jing
    Sun, Shouli
    Zhang, Yi
    CATALYSIS SCIENCE & TECHNOLOGY, 2025, 15 (07)
  • [22] Fischer-Tropsch合成
    李智渝
    沈俭一
    化学通报, 1992, (04) : 13 - 16
  • [23] Controllable Fischer-Tropsch Synthesis by In Situ-Produced 1-Olefins
    Liu, Xiaohao
    Tokunaga, Makoto
    CHEMCATCHEM, 2010, 2 (12) : 1569 - 1572
  • [24] Selective synthesis of higher linear α-olefins over cobalt Fischer-Tropsch catalyst
    Linghu, WS
    Liu, XH
    Li, XH
    Fujimoto, K
    CATALYSIS LETTERS, 2006, 108 (1-2) : 11 - 13
  • [25] Fischer-Tropsch Synthesis for Light Olefins from Syngas: A Review of Catalyst Development
    Yahyazadeh, Arash
    Dalai, Ajay K.
    Ma, Wenping
    Zhang, Lifeng
    REACTIONS, 2021, 2 (03): : 227 - 257
  • [26] Promotional effects of multiwalled carbon nanotubes on iron catalysts for Fischer-Tropsch to olefins
    Zhang, Zhengpai
    Zhang, Jun
    Wang, Xu
    Si, Rui
    Xu, Jing
    Han, Yi-Fan
    JOURNAL OF CATALYSIS, 2018, 365 : 71 - 85
  • [27] Co2C nanostructures with facet effect for Fischer-Tropsch to olefins
    Yu, Fei
    An, Yunlei
    Li, Zhengjia
    Zhong, Liangshu
    Sun, Yuhan
    ABSTRACTS OF PAPERS OF THE AMERICAN CHEMICAL SOCIETY, 2017, 253
  • [28] Distillate production by oligomerization of Fischer-Tropsch olefins over solid phosphoric acid
    de Klerk, A
    ENERGY & FUELS, 2006, 20 (02) : 439 - 445
  • [29] Experimental investigation and modeling of steam cracking of Fischer-Tropsch naphtha for light olefins
    Wang, Feng
    Xu, Yuanyuan
    Ren, Jie
    Li, Yongwang
    CHEMICAL ENGINEERING AND PROCESSING-PROCESS INTENSIFICATION, 2010, 49 (01) : 51 - 58
  • [30] Recent advances in iron-based catalysts for Fischer-Tropsch to olefins reaction
    Gao, Yulong
    Shao, Long
    Yang, Shaoqi
    Hu, Jianjun
    Zhao, Shuheng
    Dang, Jiatao
    Wang, Wei
    Yan, Xiaoyu
    Yang, Panbo
    CATALYSIS COMMUNICATIONS, 2023, 181