Multipolymers with Fischer-Tropsch olefins

被引：10

作者：

Tincul, I ^{[1
]}

Smith, J ^{[1
]}

van Zyl, P ^{[1
]}

机构：

[1] Sasol Technol R&D, ZA-1947 Sasolburg, South Africa

来源：

MACROMOLECULAR SYMPOSIA | 2003年 / 193卷

关键词：

D O I：

10.1002/masy.200390047

中图分类号：

O63 [高分子化学（高聚物）];

学科分类号：

070305 ; 080501 ; 081704 ;

摘要：

Multipolymers consisting of ethylene, 1-heptene, 3-methylpentene and 4-methylpentene were prepared with a heterogeneous Ziegler-Natta catalyst. The polymers were prepared in such a way that the molar fraction of the comonomers remained the same. Copolymers of ethylene/1-heptene and ethylene/4-methylpentene were prepared in order to study the changes in polymer characteristics as one moves from an ethylene/linear alpha olefin copolymer through ethylene multipolymers to an ethylene/4-methylpentene copolymer. The mechanical, rheological and application properties showed expected trends.

引用

页码：13 / 28

页数：16

共 50 条

[1] LOWER OLEFINS VIA FISCHER-TROPSCH
BUSSEMEIER, B
FROHNING, CD
CORNILS, B
HYDROCARBON PROCESSING, 1976, 55 (11): : 105 - 112
[2] Thermal upgrading of Fischer-Tropsch olefins
de Klerk, A
ENERGY & FUELS, 2005, 19 (04) : 1462 - 1467
[3] Ethylene copolymers with Fischer-Tropsch Olefins
Joubert, D
Tincul, I
MACROMOLECULAR SYMPOSIA, 2002, 178 : 69 - 79
[4] THE FORMATION OF ALCOHOLS AND OLEFINS WITH FISCHER-TROPSCH CATALYSTS
GIBSON, EJ
CHEMISTRY & INDUSTRY, 1957, (21) : 649 - 650
[5] Hydroformylation of olefins produced in the Fischer-Tropsch synthesis
Noskov, Yu. G.
Kron, T. E.
Karchevskaya, O. G.
Rush, S. N.
Marochkin, D. V.
Korneeva, G. A.
Mikhailov, M. N.
Bedrina, I. M.
Grigor'ev, D. A.
Bessudnov, A. E.
RUSSIAN CHEMICAL BULLETIN, 2019, 68 (09) : 1662 - 1668
[6] Fischer-Tropsch Catalyst Converts Biomass into Light Olefins
不详
CHEMICAL ENGINEERING PROGRESS, 2012, 108 (04) : 10 - +
[7] Olefins production from cracking of a Fischer-Tropsch naphtha
Fonseca, N.
dos Santos, L. R. M.
Cerqueira, H. S.
Lemos, F.
Ramoa-Ribeiro, F.
Lam, Y. L.
de Almeida, M. B. B.
FUEL, 2012, 95 (01) : 183 - 189
[8] Degradation of polyolefins prepared with Fischer-Tropsch derived olefins
Tincul, I
Govender, VT
MACROMOLECULAR SYMPOSIA, 2005, 225 : 179 - 189
[9] Particle Size Effects of Cobalt Carbide for Fischer-Tropsch to Olefins
Dai, Yuanyuan
Zhao, Yonghui
Lin, Tiejun
Li, Shenggang
Yu, Fei
An, Yunlei
Wang, Xinxing
Xiao, Kang
Sun, Fanfei
Jiang, Zheng
Lu, Yongwu
Wang, Hui
Zhong, Liangshu
Sun, Yuhan
ACS CATALYSIS, 2019, 9 (02): : 798 - 809
[10] Polymerization with Fischer-Tropsch olefins - A new challenge in polymer science
Tincul, I
Lufuno, S
Rawatlal, R
MACROMOLECULAR SYMPOSIA, 2004, 213 : 357 - 365

← 1 2 3 4 5 →