Hydrogen production with a solar steam-methanol reformer and colloid nanocatalyst

被引:27
|
作者
Lee, Ming-Tsang [1 ]
Werhahn, Michael [2 ]
Hwang, David J. [1 ]
Hotz, Nico [1 ]
Greif, Ralph [1 ]
Poulikakos, Dimos [2 ]
Grigoropoulos, Costas P. [1 ]
机构
[1] Univ Calif Berkeley, Dept Mech Engn, Laser Thermal Lab, Berkeley, CA 94720 USA
[2] ETH, Dept Mech & Proc Engn, Lab Thermodynam Emerging Technol, CH-8092 Zurich, Switzerland
关键词
Hydrogen; Nanocatalyst; Solar steam reformer; Methanol conversion; Fuel cell; CU/ZNO/AL2O3; CATALYSTS; FUELS;
D O I
10.1016/j.ijhydene.2009.10.083
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
In the present study a small steam-methanol reformer with a colloid nanocatalyst is utilized to produce hydrogen. Radiation from a focused continuous green light laser (514 nm wavelength) is used to provide the energy for steam-methanol reforming. Nanocatalyst particles, fabricated by using pulsed laser ablation technology, result in a highly active catalyst with high surface to volume ratio. A small novel reformer fabricated with a borosilicate capillary is employed to increase the local temperature of the reformer and thereby increase hydrogen production. The hydrogen production output efficiency is determined and a value of 5% is achieved. Experiments using concentrated solar simulator light as the radiation source are also carried out. The results show that hydrogen production by solar steam-methanol colloid nanocatalyst reforming is both feasible and promising. (C) 2009 Professor T. Nejat Veziroglu. Published by Elsevier Ltd. All rights reserved.
引用
收藏
页码:118 / 126
页数:9
相关论文
共 50 条
  • [1] Hydrogen production with CuO/ZnO nanowire catalyst for a nanocatalytic solar thermal steam-methanol reformer
    Nakajima, Hironori
    Lee, Daeho
    Lee, Ming-Tsang
    Grigoropoulos, Costas P.
    [J]. INTERNATIONAL JOURNAL OF HYDROGEN ENERGY, 2016, 41 (38) : 16927 - 16931
  • [2] Hydrogen production from steam-methanol reforming: thermodynamic analysis
    Lwin, Y
    Daud, WRW
    Mohamad, AB
    Yaakob, Z
    [J]. INTERNATIONAL JOURNAL OF HYDROGEN ENERGY, 2000, 25 (01) : 47 - 53
  • [3] A study of the transport phenomena in a wall-coated micro steam-methanol reformer
    Lee, Ming-Tsang
    Grigoropoulos, Costas P.
    Greif, Ralph
    [J]. INTERNATIONAL JOURNAL OF HYDROGEN ENERGY, 2014, 39 (05) : 2008 - 2017
  • [4] Computational study of the segmental catalysis of steam-methanol reforming in heat integrated microchannel reactors for hydrogen production
    Chen, Junjie
    Ge, Wei
    [J]. CHEMICAL ENGINEERING AND PROCESSING-PROCESS INTENSIFICATION, 2023, 186
  • [5] Effects of Stack Structure and Heat Loss on the Stability and Efficiency of Steam-Methanol Reforming Microreactors for Hydrogen Production
    Chen, Junjie
    Miao, Zikun
    [J]. INDUSTRIAL & ENGINEERING CHEMISTRY RESEARCH, 2023, 62 (18) : 7197 - 7211
  • [6] Integrated Methanol Steam Reformer/Electrochemical Hydrogen Compressor
    Chen, R.
    Fan, R.
    Duong, H. H.
    Chisholm, C. R. I.
    Kaye, I. W.
    [J]. POLYMER ELECTROLYTE FUEL CELLS 13 (PEFC 13), 2013, 58 (01): : 175 - 181
  • [7] Effect of catalytic washcoat shape and properties on mass transfer characteristics of microstructured steam-methanol reformers for hydrogen production
    Chen, Junjie
    Li, Tengfei
    [J]. INTERNATIONAL JOURNAL OF HYDROGEN ENERGY, 2022, 47 (37) : 16375 - 16397
  • [8] Steam-methanol reforming over zeolitic materials
    Laniecki, M
    Kazmierczak-Rosik, K
    [J]. HYDROGEN ENERGY PROGRESS XII, VOLS 1-3, 1998, : 661 - 668
  • [9] Biogas steam reformer for hydrogen production: Evaluation of the reformer prototype and catalysts
    Tuna, Celso Eduardo
    Silveira, Jose Luz
    da Silva, Marcio Evaristo
    Boloy, Ronney Mancebo
    Braga, Lucia Bolini
    Perez, Nestor Proenza
    [J]. INTERNATIONAL JOURNAL OF HYDROGEN ENERGY, 2018, 43 (04) : 2108 - 2120
  • [10] The effects of geometric and operating conditions on the hydrogen production performance of a micro-methanol steam reformer
    Jang, Jiin-Yuh
    Huang, Yu-Xian
    Cheng, Chin-Hsiang
    [J]. CHEMICAL ENGINEERING SCIENCE, 2010, 65 (20) : 5495 - 5506