In situ production of titanium dioxide nanoparticles in molten salt phase for thermal energy storage and heat-transfer fluid applications

被引:52
|
作者
Lasfargues, Mathieu [1 ]
Bell, Andrew [1 ]
Ding, Yulong [2 ]
机构
[1] Univ Leeds, Sch Chem & Proc Engn, Leeds LS2 9JT, W Yorkshire, England
[2] Univ Birmingham, Sch Chem Engn, Birmingham B15 2TT, W Midlands, England
基金
英国工程与自然科学研究理事会;
关键词
Molten salt; Nanoparticles; Specific heat capacity; Nitrate salt; Heat-transfer fluid; Nanoparticle production; CONDUCTIVITY ENHANCEMENT; NANOFLUIDS; CAPACITY; DISPERSION; SUSPENSIONS; VISCOSITY; PARTICLE;
D O I
10.1007/s11051-016-3460-8
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
In this study, TiO2 nanoparticles (average particle size 16 nm) were successfully produced in molten salt phase and were showed to significantly enhance the specific heat capacity of a binary eutectic mixture of sodium and potassium nitrate (60/40) by 5.4 % at 390 degrees C and 7.5 % at 445 degrees C for 3.0 wt% of precursors used. The objective of this research was to develop a cost-effective alternate method of production which is potentially scalable, as current techniques utilized are not economically viable for large quantities. Enhancing the specific heat capacity of molten salt would promote more competitive pricing for electricity production by concentrating solar power plant. Here, a simple precursor (TiOSO4) was added to a binary eutectic mixture of potassium and sodium nitrate, heated to 450 degrees C, and cooled to witness the production of nanoparticles.
引用
收藏
页数:11
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