Kinetics of the reaction of 2,3,5,6-tetrachloro-1,4-benzoquinone with imidazole in acetonitrile and benzene

被引：0

作者：

Dworniczak, M ^{[1
]}

Przybyszewska, M ^{[1
]}

Jarczewski, A ^{[1
]}

机构：

[1] Adam Mickiewicz Univ, Fac Chem, PL-60780 Poznan, Poland

来源：

POLISH JOURNAL OF CHEMISTRY | 1998年 / 72卷 / 01期

关键词：

kinetics; activation parameters; mechanism; solvent effect; charge transfer;

D O I：

暂无

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Nucleophilic vinylic substitution of 2,3,5,6-tetrachloro-1,4-benzoquinone by imidazole in acetonitrile and benzene has been studied spectrophotometrically. The reaction product is the diaminodichlorosubstituted quinone. The values of the activation parameters indicate that there is a considerable charge separation in the transition state. The reaction mechanism is discussed.

引用

页码：108 / 112

页数：5

共 50 条

[31] KINETICS OF THE REACTION OF 2,6-DIPHENYL-1,4-BENZOQUINONE WITH N,N,N',N'-TETRAMETHYL-P-PHENYLENEDIAMINE IN ACETONITRILE
LEVIN, PP
KHUDIAKOV, IV
KUZMIN, VA
DOKLADY AKADEMII NAUK SSSR, 1979, 246 (01): : 144 - 146
[32] INTERACTION BETWEEN POLYMERIZATION INITIATORS AND INHIBITORS IN SOLUTION .7. REACTION OF DIAZOAMINOBENZENE WITH 1,4-BENZOQUINONE, 2,5-DICHLORO-1,4-BENZOQUINONE, AND CHLORANIL IN CHLOROBENZENE AND ACETONITRILE
YASSIN, AA
MAKROMOLEKULARE CHEMIE-MACROMOLECULAR CHEMISTRY AND PHYSICS, 1975, 176 (09): : 2571 - 2578
[33] CHLORINATED DERIVATIVES OF 1,4-BENZOQUINONE .3. REDETERMINATION OF CYSTAL STRUCTURE OF 2,5-DICHLORO-1,4-BENZOQUINONE AND 2,3-DICHLORO-1,4-BENZOQUINONE
REES, B
ACTA CRYSTALLOGRAPHICA SECTION B-STRUCTURAL CRYSTALLOGRAPHY AND CRYSTAL CHEMISTRY, 1970, B 26 : 1304 - &
[34] MUTAGENICITY OF TRENIMON AND 2,3,5,6-TETRAETHYLENEIMINO-1,4-BENZOQUINONE (TEB) AT THE AD-3 REGION OF NEUROSPORA-CRASSA
BROCKMAN, HE
HUNG, CY
ONG, TM
SERRES, FJD
ENVIRONMENTAL MUTAGENESIS, 1980, 2 (02): : 241 - 242
[35] N-ACETYL-2,3,5,6-TETRACHLORO-PARA-BENZOQUINONE IMINE
FERNANDO, RC
CALDER, IC
AUSTRALIAN JOURNAL OF CHEMISTRY, 1980, 33 (10) : 2299 - 2305
[36] The polymerization of butadiene by bis(η3-allylnickeltrifluoro-acetate)/tetrachloro-1,4-benzoquinone revisited
Winter, H
Aagaard, O
MACROMOLECULAR RAPID COMMUNICATIONS, 1998, 19 (07) : 345 - 348
[37] Theoretical Study on Chemiluminescence of H2O2-dependent Tetrachloro-1,4-benzoquinone
Tang, Yi-Qi
Liu, Ya-Jun
JOURNAL OF ORGANIC CHEMISTRY, 2020, 85 (14): : 9042 - 9050
[38] PROTONATION AND METHYLATION OF ETA-4-2,3,5,6-TETRAMETHYL-1,4-BENZOQUINONE ETA-5-PENTAMETHYLCYCLOPENTADIENYL)COBALT
FAIRHURST, G
WHITE, C
JOURNAL OF ORGANOMETALLIC CHEMISTRY, 1978, 160 (02) : C17 - C20
[39] KINETICS AND MECHANISM OF PHOTOLYSIS OF 2,6-DI-TERT-BUTYL-1,4-BENZOQUINONE DIAZIDE IN BENZENE AND DEUTEROBENZENE
YANKELEVICH, AZ
SERGEEV, AM
RYKOV, SV
POTAPOV, VK
NIKIFOROV, GA
BULLETIN OF THE ACADEMY OF SCIENCES OF THE USSR DIVISION OF CHEMICAL SCIENCE, 1986, 35 (12): : 2457 - 2461
[40] Photoreactions of 2-methyl-5-isopropyl-1,4-benzoquinone
Görner, H
JOURNAL OF PHOTOCHEMISTRY AND PHOTOBIOLOGY A-CHEMISTRY, 2004, 165 (1-3) : 215 - 222

← 1 2 3 4 5 →