The selective functionalization of saturated hydrocarbons. Part 46. An investigation of Udenfriend's system under Gif conditions.

被引：2

作者：

Barton, DHR ^{[1
]}

Delanghe, NC ^{[1
]}

机构：

[1] Texas A&M Univ, Dept Chem, College Stn, TX 77842 USA

来源：

TETRAHEDRON | 1998年 / 54卷 / 18期

基金：

美国国家科学基金会;

关键词：

D O I：

10.1016/S0040-4020(98)00163-X

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Under Gif conditions using ascorbic acid as reductant and oxygen as oxidant in pyridine, the selectivity for secondary hydrogen functionalization is exceptional. EDTA (ethylenediamine-tetra-acetic acid) is not needed as a ligand for iron. (C) 1998 Elsevier Science Ltd. All rights reserved.

引用

页码：4471 / 4476

页数：6

共 13 条

[1] The selective functionalization of saturated hydrocarbons. Part 43. Modified Gif oxidation in acetonitrile
Barton, DHR
Li, TS
TETRAHEDRON, 1998, 54 (09) : 1735 - 1744
[2] The Selective Functionalization of Saturated Hydrocarbons. Part 43. Modified Gif Oxidation in Acetonitrile
Tetrahedron, 9 (1735):
[3] The Selective Functionalization of Saturated Hydrocarbons. Part 42. Further Studies in Selective Phenylselenation
Barton, D. H. R.
Lalic, G.
Smith, J. A.
Tetrahedron, 54 (09):
[4] The selective functionalization of saturated hydrocarbons. Part 42. Further studies in selective phenylselenation.
Barton, DHR
Lalic, G
Smith, JA
TETRAHEDRON, 1998, 54 (09) : 1725 - 1734
[5] The selective functionalization of saturated hydrocarbons. Part 44. Measurement of size of reagent by variation of steric demands of competing substrates using Gif chemistry
Tetrahedron, 14 (3379):
[6] A NEW HETEROGENEOUS SYSTEM FOR THE SELECTIVE FUNCTIONALIZATION OF SATURATED-HYDROCARBONS - THE GIF-KRICT SYSTEM
LEE, KW
KIM, SB
JUN, KW
SHIM, EK
NEW JOURNAL OF CHEMISTRY, 1993, 17 (06) : 409 - 411
[7] The Functionalization of Saturated Hydrocarbons. Part 39. Further Evidence for the Role of the Iron-Carbon Bond in Gif Chemistry
Tetrahedron, 22 (7417):
[8] The selective functionalization of saturated hydrocarbons. Part 44. Measurement of size of reagent by variation of steric demands of competing substrates using Gif chemistry.
Barton, DHR
Launay, F
TETRAHEDRON, 1998, 54 (14) : 3379 - 3390
[9] Functionalization of saturated hydrocarbons. Part 20. Alkyl hydroperoxides. Reaction intermediates in the oxidation of saturated hydrocarbons by Gif-type reactions and mechanistic studies on their formation
Barton, Derek H.R.
Beviere, Stephane D.
Chavashri, Warinthorn
Csubai, Eva
Doller, Dario
Liu, Wei-Guo
Journal of the American Chemical Society, 1992, 114 (06):
[10] The selective functionalization of saturated hydrocarbons.: Part 47.: Investigation of the size of the reagent involved in the FeII-FeIV manifold.
Barton, DHR
Launay, F
TETRAHEDRON, 1998, 54 (42) : 12699 - 12706

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