Nickel-catalyzed and benzoic acid-promoted direct sulfenylation of unactivated arenes

被引：106
|
作者：
Yang, Ke [1 ]
Wang, Yuqi [1 ]
Chen, Xinyong [1 ]
Kadi, Adnan A. [2 ]
Fun, Hoong-Kun [2 ]
Sun, Hao [1 ]
Zhang, Yan [1 ,2 ]
Lu, Hongjian [1 ]
机构：
[1] Nanjing Univ, Sch Chem & Chem Engn, Inst Chem BioMed Sci, Nanjing 210093, Jiangsu, Peoples R China
[2] King Saud Univ, Coll Pharm, Dept Pharmaceut Chem, Riyadh 11451, Saudi Arabia
来源：
CHEMICAL COMMUNICATIONS | 2015年 / 51卷 / 17期
基金：
中国国家自然科学基金;
关键词：
C-H BOND; COUPLING REACTIONS; DIRECT THIOLATION; C(SP(3))-H BONDS; ARYL HALIDES; COPPER; FUNCTIONALIZATION; ACTIVATION; EFFICIENT; ARYLATION;
D O I：
10.1039/c4cc10431e
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
A nickel-catalyzed and benzoic acid-promoted direct sulfenylation of unactivated arenes using removable 2-(pyridine-2-yl)-isopropylamine as a directing group is described. This strategy provides an efficient access to valuable aryl sulfides with ample substrate scope and a high degree of functional group tolerance.
引用
收藏
页码：3582 / 3585
页数：4
相关论文
共 50 条
  • [1] Nickel-catalyzed direct C-H arylation of unactivated arenes with aryl halides
    Xie, Guanlei
    Li, Tingyi
    Qu, Xiaoming
    Mao, Jincheng
    JOURNAL OF MOLECULAR CATALYSIS A-CHEMICAL, 2011, 340 (1-2) : 48 - 52
  • [2] Nickel-Catalyzed Direct Amination of Arenes with Alkylamines
    Yan, Qiangqiang
    Chen, Zhengkai
    Yu, Wenlong
    Yin, Hong
    Liu, Zhanxiang
    Zhang, Yuhong
    ORGANIC LETTERS, 2015, 17 (10) : 2482 - 2485
  • [3] Bronsted acid-promoted cyclizations of siloxy alkynes with unactivated arenes, alkenes, and alkynes
    Zhang, Liming
    Sun, Jianwei
    Kozmin, Sergey A.
    TETRAHEDRON, 2006, 62 (49) : 11371 - 11380
  • [4] Nickel-catalyzed direct C-H bond sulfenylation of acylhydrazines
    Li, Jun-Ming
    Yu, Yang
    Weng, Jiang
    Lu, Gui
    ORGANIC & BIOMOLECULAR CHEMISTRY, 2018, 16 (33) : 6047 - 6056
  • [5] Iridium-Promoted, Palladium-Catalyzed Direct Arylation of Unactivated Arenes
    Durak, Landon J.
    Lewis, Jared C.
    ORGANOMETALLICS, 2014, 33 (03) : 620 - 623
  • [6] Ir-promoted, Pd-catalyzed direct arylation of unactivated arenes
    Durak, Landon J.
    Lewis, Jared C.
    ABSTRACTS OF PAPERS OF THE AMERICAN CHEMICAL SOCIETY, 2014, 247
  • [7] Nickel-catalyzed olefination of unactivated aliphatic dithioacetals
    Huang, LF
    Huang, CH
    Stulgies, B
    de Meijere, A
    Luh, TY
    ORGANIC LETTERS, 2003, 5 (23) : 4489 - 4491
  • [8] Nickel-Catalyzed Direct Sulfonylation of Styrenes and Unactivated Aliphatic Alkenes with Sulfonyl Chlorides
    Rao, Wei-Hao
    Li, Ying-Ge
    Jiang, Li-Li
    Gao, Chang
    Wang, Yi-Zhuo
    Liu, Jia-Fan
    Zhou, Fu-Yu
    Zou, Guo-Dong
    Cao, Xinhua
    JOURNAL OF ORGANIC CHEMISTRY, 2024, 89 (14): : 9755 - 9768
  • [9] Nickel-Catalyzed Stereoselective Arylboration of Unactivated Alkenes
    Logan, Kaitlyn M.
    Sardini, Stephen R.
    White, Sean D.
    Brown, M. Kevin
    JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2018, 140 (01) : 159 - 162
  • [10] Nickel-Catalyzed Exhaustive Hydrodefluorination of Perfluoroalkyl Arenes
    Doi, Ryohei
    Yasuda, Masashi
    Kajita, Naoki
    Koh, Kenta
    Ogoshi, Sensuke
    JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2023, 145 (20) : 11449 - 11456
12345