Development of ceria-doped zirconia electrolytes with high toughness and ionic conductivity

被引:10
|
作者
Yeh, Tsung-Her [1 ]
Chou, Chen-Chia [1 ]
机构
[1] Natl Taiwan Univ Sci & Technol, Dept Mech Engn, Taipei 10672, Taiwan
关键词
Mechanical properties; Electrical properties; Electrolyte; Toughness; Bending strength; ELECTRICAL-PROPERTIES; TETRAGONAL ZIRCONIA; FRACTURE; CERAMICS;
D O I
10.1016/j.ssi.2009.08.012
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
Development Of Y2O3 stabilized ZrO2 electrolytes for solid oxide fuel cell with better mechanical properties was attempted. 3 mol% Y2O3 stabilized ZrO2 doped with 3-15 mol% CeO2 was investigated in the present work. The results reveal that the toughness and the bending strength of 3-6 mol% CeO2 doped 3 mol% Y2O3-ZrO2 are much higher than that of 8 mol% Y2O3-ZrO2. The best ionic conductivity observed in 6 mol% ceria-doped 3 mol% Y2O3-ZrO2 electrolyte is better than that of 8 mol% Y2O3-ZrO2 at 800 degrees C, which indicates the possibility of developing ZrO2-based electrolyte with enhanced toughness. (C) 2009 Published by Elsevier B.V.
引用
收藏
页码:1529 / 1533
页数:5
相关论文
共 50 条
  • [21] Effect of manganese oxide on the densification and properties of ceria-doped scandia stabilized zirconia
    Ng, C. K.
    Ramesh, S.
    Tan, C. Y.
    Ching, C. Y.
    Lwin, N.
    Muchtar, A.
    JOURNAL OF CERAMIC PROCESSING RESEARCH, 2016, 17 (05): : 443 - 447
  • [22] Optimization of ionic conductivity in doped ceria
    Andersson, DA
    Simak, SI
    Skorodumova, NV
    Abrikosov, IA
    Johansson, B
    PROCEEDINGS OF THE NATIONAL ACADEMY OF SCIENCES OF THE UNITED STATES OF AMERICA, 2006, 103 (10) : 3518 - 3521
  • [23] PREPARATION OF SPHERICAL CERIA-DOPED TETRAGONAL ZIRCONIA BY THE SPRAY-PYROLYSIS METHOD
    YOSHIOKA, T
    DOSAKA, K
    SATO, T
    OKUWAKI, A
    TANNO, S
    MIURA, T
    JOURNAL OF MATERIALS SCIENCE LETTERS, 1992, 11 (01) : 51 - 55
  • [24] Interface Effects on the Ionic Conductivity of Doped Ceria-Yttria-Stabilized Zirconia Heterostructures
    Pergolesi, Daniele
    Gilardi, Elisa
    Fabbri, Emiliana
    Roddatis, Vladimir
    Harrington, George F.
    Lippert, Thomas
    Kilner, John A.
    Traversa, Enrico
    ACS APPLIED MATERIALS & INTERFACES, 2018, 10 (16) : 14160 - 14169
  • [25] Strengthening of ceria-doped tetragonal zirconia polycrystals by reduction-induced Phase transformation
    Heussner, Karl-Heinz
    Claussen, Nils
    Journal of the American Ceramic Society, 1989, 72 (06): : 1044 - 1046
  • [26] Mechanical Properties of Ceria-doped Scandia-stabilized Zirconia Electrolyte Coatings for SOFCs
    Zhang, X.
    Smirnova, A.
    Sammes, N.
    Brodnikovskii, E.
    Vasylyev, A.
    SOLID OXIDE FUEL CELLS 10 (SOFC-X), PTS 1 AND 2, 2007, 7 (01): : 2233 - +
  • [27] Ionic conductivity of Gd- and Y-doped ceria-zirconia solid solutions
    Ruehrup, Vera
    Wiemhoefer, Hans-Dieter
    ZEITSCHRIFT FUR NATURFORSCHUNG SECTION B-A JOURNAL OF CHEMICAL SCIENCES, 2006, 61 (07): : 916 - 922
  • [28] Processing and microstructure characterization of ceria-doped yttria-stabilized zirconia powder and ceramics
    Bekale, V. Menvie
    Legros, C.
    Haut, C.
    Sattonnay, G.
    Huntz, A. M.
    SOLID STATE IONICS, 2006, 177 (37-38) : 3339 - 3347
  • [29] SINTERING OF CERIA-DOPED TETRAGONAL ZIRCONIA CRYSTALLIZED IN ORGANIC-SOLVENTS, WATER, AND AIR
    SATO, T
    DOSAKA, K
    YOSHIOKA, T
    OKUWAKI, A
    TORII, K
    ONODERA, Y
    JOURNAL OF THE AMERICAN CERAMIC SOCIETY, 1992, 75 (03) : 552 - 556
  • [30] The ionic conductivity of Sm-doped ceria
    Koettgen, Julius
    Martin, Manfred
    JOURNAL OF THE AMERICAN CERAMIC SOCIETY, 2020, 103 (06) : 3776 - 3787