The optical nonlinear properties of a new synthesized azo-nitrone compound

被引:37
|
作者
Mutlaq, Dakhil Zughayir [1 ]
Hassan, Qusay M. A. [2 ]
Sultan, H. A. [2 ]
Emshary, C. A. [2 ]
机构
[1] Univ Basrah, Coll Educ Pure Sci, Dept Chem, Basrah, Iraq
[2] Univ Basrah, Coll Educ Pure Sci, Dept Phys, Basrah, Iraq
关键词
Azo-nitrone; Diffraction ring pattern; Z-scan; Nonlinear refractive index; Simulation results; Optical limiting; FIELD DIFFRACTION PATTERNS; LIMITING PROPERTIES; CONTINUOUS-WAVE; SECONDARY-AMINES; ORGANIC-DYE; 532; NM; OXIDATION; HYDROXYLAMINES; PHTHALOCYANINE; DERIVATIVES;
D O I
10.1016/j.optmat.2021.110815
中图分类号
T [工业技术];
学科分类号
08 ;
摘要
In this article the preparation of compound heterogeneous azo-nitrone is introduced. Novel compound resulted via the reaction between azoaldehyde and N-phenylhydroxylamine through several steps. (Z)-1-(2-hydroxy-3-methoxy-5-((E)-(3-nitrophenyl) diazenyl) phenyl)-N-phenylmethanimine oxide derived from N-phenylhydroxylamine with (E)-2-hydroxy-3-methoxy-5-((3-nitrophenyl) diazenyl) benzaldehyde. The novel azo-nitrone compound has been identified via infrared spectroscopy (FT-IR), NMR proton spectrum (H-1 NMR) and mass spectrometry (Mass spectra) as well as measurement of its melting point. The nonlinear index of refraction of the prepared compound is determined separately via the patterns of diffraction ring and the Z-scan. Ring patterns are simulated using the Fresnel-Kirchhoff diffraction theory. The optical limiting property of the prepared compound is tested where it is proved that such compound might be used as an optical limiter.
引用
收藏
页数:13
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