Phosphine-Catalyzed Reactions with Unsaturated Carbonyl Compounds

被引：21

作者：

Nallapati, Suresh Babu ^{[1
]}

Chuang, Shih-Ching ^{[1
]}

机构：

[1] Natl Chiao Tung Univ, Dept Appl Chem, Hsinchu 300, Taiwan

来源：

ASIAN JOURNAL OF ORGANIC CHEMISTRY | 2018年 / 7卷 / 09期

关键词：

phosphine; anti-Michael addition; catalysis; fullerenes; organic photovoltaics; ASYMMETRIC 3+2 ANNULATIONS; ADDITION-DELTA-EVOLVEMENT; 3-COMPONENT REACTION; MULTICOMPONENT REACTIONS; PHOSPHORUS YLIDES; BAYLIS-HILLMAN; GAMMA-LACTAMS; DIASTEREOSELECTIVE SYNTHESIS; ENANTIOSELECTIVE SYNTHESIS; CONVENIENT SYNTHESIS;

D O I：

10.1002/ajoc.201800325

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Organophosphines are versatile Lewis basic catalysts that have been confirmed as powerful tools in organic synthesis for the past two decades. The nucleophilic addition of organophosphines to electron-deficient species can be divided into two categories: phosphine-catalyzed and stoichiometric phosphine-mediated transformations. In this focus review, we summarize recent examples of phosphine-catalyzed addition and annulation reactions with allenoates and alkynoates. In addition, we discuss our recent efforts in the development of unusual phosphine-mediated alpha-addition reactions with enynedioates, enynoates, and oligoynoates and its application in novel functional fullerene derivatives as n-type materials in organic photovoltaics.

引用

页码：1743 / 1757

页数：15

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