Phosphine-Catalyzed Reactions with Unsaturated Carbonyl Compounds

被引：21
|
作者：
Nallapati, Suresh Babu [1 ]
Chuang, Shih-Ching [1 ]
机构：
[1] Natl Chiao Tung Univ, Dept Appl Chem, Hsinchu 300, Taiwan
来源：
ASIAN JOURNAL OF ORGANIC CHEMISTRY | 2018年 / 7卷 / 09期
关键词：
phosphine; anti-Michael addition; catalysis; fullerenes; organic photovoltaics; ASYMMETRIC 3+2 ANNULATIONS; ADDITION-DELTA-EVOLVEMENT; 3-COMPONENT REACTION; MULTICOMPONENT REACTIONS; PHOSPHORUS YLIDES; BAYLIS-HILLMAN; GAMMA-LACTAMS; DIASTEREOSELECTIVE SYNTHESIS; ENANTIOSELECTIVE SYNTHESIS; CONVENIENT SYNTHESIS;
D O I：
10.1002/ajoc.201800325
中图分类号：
O62 [有机化学];
学科分类号：
070303 ; 081704 ;
摘要：
Organophosphines are versatile Lewis basic catalysts that have been confirmed as powerful tools in organic synthesis for the past two decades. The nucleophilic addition of organophosphines to electron-deficient species can be divided into two categories: phosphine-catalyzed and stoichiometric phosphine-mediated transformations. In this focus review, we summarize recent examples of phosphine-catalyzed addition and annulation reactions with allenoates and alkynoates. In addition, we discuss our recent efforts in the development of unusual phosphine-mediated alpha-addition reactions with enynedioates, enynoates, and oligoynoates and its application in novel functional fullerene derivatives as n-type materials in organic photovoltaics.
引用
收藏
页码：1743 / 1757
页数：15
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