Synthesis and application of a stable nonlinear optical polymer

被引：7
|
作者：
Zhang, DM [1 ]
Sun, JZ
Hou, AL
Shen, JC
Yi, MB
机构：
[1] Jilin Univ, State Key Lab Integrated Optoelect, Changchun 130023, Peoples R China
[2] Jilin Univ, Key Lab Supramol Struct & Spect, Changchun 130023, Peoples R China
来源：
MATERIALS LETTERS | 2000年 / 45卷 / 3-4期
基金：
中国国家自然科学基金;
关键词：
nonlinear optics; electro-optic effect; polymer applications; photo-cross-linking;
D O I：
10.1016/S0167-577X(00)00095-1
中图分类号：
T [工业技术];
学科分类号：
08 ;
摘要：
A photo-cross-linked side-chain second-order nonlinear optical polymer was synthesized with bis-phenol-A as the polymer backbone. The characterization of the polymer was done by nuclear magnetic resonance, infrared spectra, ultraviolet spectra and dynamic mechanical analysis methods. The electro-optic film was obtained by spin-coating and corona poling then photo-cross-linked. The film showed high glass transition temperature (160 degrees C) and improved chromophore orientation stability. An electro-optic measuring system was established based on this film. The results showed that the film has a linear electro-optic characteristic and the voltage sensitivity was higher than that of a GaAs probe. (C) 2000 Elsevier Science B.V. All rights reserved.
引用
收藏
页码：149 / 153
页数：5
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