Synthesis of Ultrathin PdCu Alloy Nanosheets Used as a Highly Efficient Electrocatalyst for Formic Acid Oxidation

被引：267

作者：

Yang, Nailiang ^{[1
]}

Zhang, Zhicheng ^{[1
]}

Chen, Bo ^{[1
]}

Huang, Ying ^{[1
]}

Chen, Junze ^{[1
]}

Lai, Zhuangchai ^{[1
]}

Chen, Ye ^{[1
]}

Sindoro, Melinda ^{[1
]}

Wang, An-Liang ^{[1
]}

Cheng, Hongfei ^{[1
]}

Fan, Zhanxi ^{[1
]}

Liu, Xiaozhi ^{[2
,3
]}

Li, Bing ^{[4
]}

Zong, Yun ^{[4
]}

Gu, Lin ^{[2
,3
,5
]}

Zhang, Hua ^{[1
]}

机构：

[1] Nanyang Technol Univ, Sch Mat Sci & Engn, Ctr Programmable Mat, 50 Nanyang Ave, Singapore 639798, Singapore

[2] Chinese Acad Sci, Inst Phys, Beijing Natl Lab Condensed Matter Phys, Beijing 100190, Peoples R China

[3] Univ Chinese Acad Sci, Sch Phys Sci, Beijing 100049, Peoples R China

[4] ASTAR, Inst Mat Res & Engn, 2 Fusionopolis Way,Innovis 08-03, Singapore 138634, Singapore

[5] Collaborat Innovat Ctr Quantum Matter, Beijing 100190, Peoples R China

来源：

ADVANCED MATERIALS | 2017年 / 29卷 / 29期

关键词：

electrocatalysts; formic acid oxidation; nanosheets; PdCu alloy; ORGANIC-FRAMEWORK NANOSHEETS; METAL DICHALCOGENIDE NANOSHEETS; GOLD SQUARE SHEETS; PT-CU NANOSHEETS; PALLADIUM NANOSHEETS; ETHANOL-OXIDATION; OXYGEN-REDUCTION; NANOPARTICLES; SURFACE; NANOCRYSTALS;

D O I：

10.1002/adma.201700769

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Inspired by the unique properties of ultrathin 2D nanomaterials and excellent catalytic activities of noble metal nanostructures for renewable fuel cells, a facile method is reported for the high-yield synthesis of ultrathin 2D PdCu alloy nanosheets under mild conditions. Impressively, the obtained PdCu alloy nanosheet after being treated with ethylenediamine can be used as a highly efficient electrocatalyst for formic acid oxidation. The study implicates that the rational design and controlled synthesis of an ultrathin 2D noble metal alloy may open up new opportunities for enhancing catalytic activities of noble metal nanostructures.

引用

页数：6

共 50 条

[31] Self-assembly of NiFe-based ultrathin nanosheets on nickel foam as highly active and efficient electrocatalyst for water oxidation
Wang, Jianying
Chen, Zuofeng
ABSTRACTS OF PAPERS OF THE AMERICAN CHEMICAL SOCIETY, 2019, 258
[32] Controllable synthesis of ultrathin Co9S8 nanosheets as a highly efficient electrocatalyst for overall water splitting
Yang, Yan
Yuan, Mengwei
Li, Huifeng
Sun, Genban
Ma, Shulan
ELECTROCHIMICA ACTA, 2018, 281 : 198 - 207
[33] Nanoporous PdCu alloy for formic acid electro-oxidation (vol 199, pg 124, 2012)
Xu, Caixia
Liu, Yunqing
Wang, Jinping
Geng, Haoran
Qiu, Huajun
JOURNAL OF POWER SOURCES, 2013, 225 : 384 - 384
[34] Highly dispersed PdCu nanoparticles for enhanced formic acid oxidation: Ordering effect of intermetallic compound structure
Hu, Yawen
Liu, Yue
Min, Yulin
Xu, Qunjie
Jiang, Kun
Li, Qiaoxia
INTERNATIONAL JOURNAL OF HYDROGEN ENERGY, 2025, 118 : 217 - 226
[35] Synthesis of Multiple-Twinned Pd Nanoparticles Anchored on Graphitic Carbon Nanosheets for Use as Highly-Active Multifunctional Electrocatalyst in Formic Acid and Methanol Oxidation Reactions
Huang Huajie
Wei Yujie
Shen Bingfeng
Zhang Yao
He Haiyan
Jiang Quanguo
Yang Lu
Nanjundan, Ashok Kumar
Na, Jongbeom
Xu Xingtao
Zhu Jixin
Yamauchi, Yusuke
ADVANCED MATERIALS INTERFACES, 2020, 7 (11):
[36] Efficient formic acid oxidation over gallium oxide incorporated Pd containing electrocatalyst
Sofian, Muhammad
Nasim, Fatima
Ali, Hassan
Kanodarwala, Fehmida K.
Nadeem, Muhammad Arif
INTERNATIONAL JOURNAL OF HYDROGEN ENERGY, 2024, 51 : 1277 - 1285
[37] An Fe-doped NiV LDH ultrathin nanosheet as a highly efficient electrocatalyst for efficient water oxidation
Wang, Zhaolong
Liu, Wenjun
Hu, Yiming
Xu, Li
Guan, Meili
Qiu, Jingxia
Huang, Yunpeng
Bao, Jian
Li, Huaming
INORGANIC CHEMISTRY FRONTIERS, 2019, 6 (07) : 1890 - 1896
[38] Cyanogel-Induced PdCu Alloy with Pd-Enriched Surface for Formic Acid Oxidation and Oxygen Reduction
Liu, Qicheng
Li, Zhijuan
Zhou, Xinyi
Xiao, Jiayi
Han, Zheng
Jiang, Xian
Fu, Gengtao
Tang, Yawen
ADVANCED ENERGY AND SUSTAINABILITY RESEARCH, 2022, 3 (10):
[39] Highly Active PdCu Alloy Nanowire Network Electrocatalyst for Ethanol and Methanol Electrooxidation
Chen, Rongna
Sun, Muxue
Pang, Guigui
Zhou, Junshuang
Hou, Li
Gao, Faming
CHEMELECTROCHEM, 2017, 4 (05): : 1081 - 1087
[40] Ultrathin Rh nanosheets as a highly efficient bifunctional electrocatalyst for isopropanol-assisted overall water splitting
Zhao, Yue
Xing, Shihui
Meng, Xinying
Zeng, Jinghui
Yin, Shibin
Li, Xifei
Chen, Yu
NANOSCALE, 2019, 11 (19) : 9319 - 9326

← 1 2 3 4 5 →