Synthesis of Ultrathin PdCu Alloy Nanosheets Used as a Highly Efficient Electrocatalyst for Formic Acid Oxidation

被引：267

作者：

Yang, Nailiang ^{[1
]}

Zhang, Zhicheng ^{[1
]}

Chen, Bo ^{[1
]}

Huang, Ying ^{[1
]}

Chen, Junze ^{[1
]}

Lai, Zhuangchai ^{[1
]}

Chen, Ye ^{[1
]}

Sindoro, Melinda ^{[1
]}

Wang, An-Liang ^{[1
]}

Cheng, Hongfei ^{[1
]}

Fan, Zhanxi ^{[1
]}

Liu, Xiaozhi ^{[2
,3
]}

Li, Bing ^{[4
]}

Zong, Yun ^{[4
]}

Gu, Lin ^{[2
,3
,5
]}

Zhang, Hua ^{[1
]}

机构：

[1] Nanyang Technol Univ, Sch Mat Sci & Engn, Ctr Programmable Mat, 50 Nanyang Ave, Singapore 639798, Singapore

[2] Chinese Acad Sci, Inst Phys, Beijing Natl Lab Condensed Matter Phys, Beijing 100190, Peoples R China

[3] Univ Chinese Acad Sci, Sch Phys Sci, Beijing 100049, Peoples R China

[4] ASTAR, Inst Mat Res & Engn, 2 Fusionopolis Way,Innovis 08-03, Singapore 138634, Singapore

[5] Collaborat Innovat Ctr Quantum Matter, Beijing 100190, Peoples R China

来源：

ADVANCED MATERIALS | 2017年 / 29卷 / 29期

关键词：

electrocatalysts; formic acid oxidation; nanosheets; PdCu alloy; ORGANIC-FRAMEWORK NANOSHEETS; METAL DICHALCOGENIDE NANOSHEETS; GOLD SQUARE SHEETS; PT-CU NANOSHEETS; PALLADIUM NANOSHEETS; ETHANOL-OXIDATION; OXYGEN-REDUCTION; NANOPARTICLES; SURFACE; NANOCRYSTALS;

D O I：

10.1002/adma.201700769

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Inspired by the unique properties of ultrathin 2D nanomaterials and excellent catalytic activities of noble metal nanostructures for renewable fuel cells, a facile method is reported for the high-yield synthesis of ultrathin 2D PdCu alloy nanosheets under mild conditions. Impressively, the obtained PdCu alloy nanosheet after being treated with ethylenediamine can be used as a highly efficient electrocatalyst for formic acid oxidation. The study implicates that the rational design and controlled synthesis of an ultrathin 2D noble metal alloy may open up new opportunities for enhancing catalytic activities of noble metal nanostructures.

引用

页数：6

共 50 条

[1] Ultrathin PdCu alloy nanosheets for highly efficient electrocatalytic formic acid oxidation
Cheng, Hongfei
Yang, Nailiang
Zhang, Hua
ABSTRACTS OF PAPERS OF THE AMERICAN CHEMICAL SOCIETY, 2018, 256
[2] Sn-doped PdCu alloy nanosheet assemblies as an efficient electrocatalyst for formic acid oxidation
Yang, Fu-Kai
Fang, Yue
Li, Fang-Fang
Qu, Wei-Li
Deng, Chao
DALTON TRANSACTIONS, 2023, 52 (40) : 14428 - 14434
[3] Coral-like PdCu Alloy Nanoparticles Act as Stable Electrocatalysts for Highly Efficient Formic Acid Oxidation
Zheng, Jianzhong
Zeng, Huajie
Tan, Changhui
Zhang, Tingmei
Zhao, Bo
Guo, Wei
Wang, Haibo
Sun, Yinghui
Jiang, Lin
ACS SUSTAINABLE CHEMISTRY & ENGINEERING, 2019, 7 (18): : 15354 - 15360
[4] Nanoporous PdPt alloy as a highly active electrocatalyst for formic acid oxidation
Xu, Caixia
Hao, Qin
Duan, Huimei
JOURNAL OF MATERIALS CHEMISTRY A, 2014, 2 (23) : 8875 - 8880
[5] Ultrathin PdMo bimetallene immobilized on graphene nanosheets as an efficient bifunctional electrocatalyst towards formic acid and methanol oxidation reactions
Yang, Cuizhen
Wang, Tianyi
Wang, Tingyao
He, Haiyan
Liu, Dongming
Huang, Huajie
INTERNATIONAL JOURNAL OF HYDROGEN ENERGY, 2024, 80 : 1174 - 1181
[6] Facile synthesis of PdCu nanocluster-assembled granular films as highly efficient electrocatalysts for formic acid oxidation
Ding, Qing-Wei
Luo, Qing
Lin, Liang
Fu, Xing-Ping
Wang, Lai-Sen
Yue, Guang-Hui
Lin, Jie
Xie, Qing-Shui
Peng, Dong-Liang
RARE METALS, 2022, 41 (08) : 2595 - 2605
[7] Facile fabrication of stable PdCu clusters uniformly decorated on graphene as an efficient electrocatalyst for formic acid oxidation
Zhang, Zhe
Gong, Yuyan
Wu, Diben
Li, Zhi
Li, Qing
Zheng, Linwei
Chen, Wei
Yuan, Weiyong
Zhang, Lian Ying
INTERNATIONAL JOURNAL OF HYDROGEN ENERGY, 2019, 44 (05) : 2731 - 2740
[8] Ultrathin AgPt alloy nanowires as a high-performance electrocatalyst for formic acid oxidation
Xian Jiang
Gengtao Fu
Xia Wu
Yang Liu
Mingyi Zhang
Dongmei Sun
Lin Xu
Yawen Tang
Nano Research, 2018, 11 : 499 - 510
[9] Facile synthesis of PdCu nanocluster-assembled granular films as highly efficient electrocatalysts for formic acid oxidation
Qing-Wei Ding
Qing Luo
Liang Lin
Xing-Ping Fu
Lai-Sen Wang
Guang-Hui Yue
Jie Lin
Qing-Shui Xie
Dong-Liang Peng
RareMetals, 2022, 41 (08) : 2595 - 2605
[10] Facile synthesis of PdCu nanocluster-assembled granular films as highly efficient electrocatalysts for formic acid oxidation
Qing-Wei Ding
Qing Luo
Liang Lin
Xing-Ping Fu
Lai-Sen Wang
Guang-Hui Yue
Jie Lin
Qing-Shui Xie
Dong-Liang Peng
Rare Metals, 2022, 41 : 2595 - 2605

← 1 2 3 4 5 →