Synthesis, crystal and molecular structure of the first indium trihydride complex, [InH3{CN(Pri)C2Me2N(Pri)}]

被引：41
|
作者：
Hibbs, DE
Hursthouse, MB
Jones, C
Smithies, NA
机构：
[1] Univ Coll Swansea, Dept Chem, Swansea SA2 8PP, W Glam, Wales
[2] Univ Wales, Dept Chem, EPSRC Xray Crystallog Serv, Cardiff CF1 3TB, S Glam, Wales
来源：
CHEMICAL COMMUNICATIONS | 1998年 / 08期
关键词：
D O I：
10.1039/a801118d
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
The reaction of either [InH3(NMe3)] or LiInH4 with an excess of the imidazol-2-ylidene carbene, :CN(Pr-i)C2Me2N-(Pr-i), affords the first example of an indium trihydride complex, [InH3{CN(Pr-i)C2Me2N(Pr-i)}], the X-ray crystal structure of which is described.
引用
收藏
页码：869 / 870
页数：2
相关论文
共 50 条
  • [21] Synthesis and crystal structure of dinuclear zinc(II) complex with 3-Me-N-oxopyridine-2-thiol
    Niu, DZ
    Sun, BW
    Lu, ZS
    Song, BL
    CHINESE JOURNAL OF STRUCTURAL CHEMISTRY, 2001, 20 (02) : 108 - 111
  • [22] A D4-THIOLATO DINITROGEN COMPLEX - THE SYNTHESIS AND CRYSTAL-STRUCTURE OF [RE(N2)(SC6H2-2,4,6-PRI3)3(PPH3)]
    DILWORTH, JR
    HU, J
    THOMPSON, RM
    HUGHES, DL
    JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS, 1992, (07) : 551 - 553
  • [23] Synthesis and crystal structure of [N(Hex)4]∞3[Cu2(CN)3]
    Pretsch, T
    Brüdgam, I
    Hartl, H
    ZEITSCHRIFT FUR ANORGANISCHE UND ALLGEMEINE CHEMIE, 2003, 629 (06): : 942 - 944
  • [24] SYNTHESIS AND X-RAY CRYSTAL-STRUCTURE OF [CU(SC6H2PRI3)]8
    YANG, QC
    TANG, KL
    LIAO, H
    HAN, YH
    CHEN, ZG
    TANG, YQ
    JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS, 1987, (14) : 1076 - 1077
  • [25] A MONONUCLEAR VANADIUM(III) THIOLATE COMPLEX - SYNTHESIS, STRUCTURE, AND PROPERTIES OF [V(S-2,4,6-PRI3C6H2)3(THF)2]
    RANDALL, CR
    ARMSTRONG, WH
    JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS, 1988, (15) : 986 - 987
  • [26] CRYSTAL AND MOLECULAR STRUCTURE OF TETRAMETHYLFORMAMIDINIUMPHOSPHONATE, [ME2N]2CPO3H
    DALY, JJ
    JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS, 1972, (10): : 1048 - &
  • [27] Synthesis and Molecular Structure of Ph3GeBO2C2Me4
    Bowes, Eric G.
    Vogels, Christopher M.
    Decken, Andreas
    Westcott, Stephen A.
    X-RAY STRUCTURE ANALYSIS ONLINE, 2016, 32 : 35 - 36
  • [28] The synthesis and structure of lithium derivatives of the sterically encumbered β-diketiminate ligand [{(2,6-Pri2H3C6)N(CH3)C}2CH]-, and a modified synthesis of the aminoimine precursor
    Stender, M
    Wright, RJ
    Eichler, BE
    Prust, J
    Olmstead, MM
    Roesky, HW
    Power, PP
    JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS, 2001, (23): : 3465 - 3469
  • [29] New Organophosphorus Proligands and Amide Precursors: Crystal and Molecular Structures of Ph2P(X)NH(C6H3Pri2-2,6) (X = O, S) and (OPPh2)(O2SMe)N(C6H3Pri2-2,6)
    Pollnitz, Alpar
    Irisli, Sevil
    Silvestru, Cristian
    Silvestru, Anca
    PHOSPHORUS SULFUR AND SILICON AND THE RELATED ELEMENTS, 2010, 185 (04) : 910 - 919
  • [30] Synthesis and crystal structure of a novel decanuclear silver cluster complex [Ag(SC6H2Pri3-2,4,6)]10•2CHCl3•C2H5OH
    Jin, XL
    Xie, XJ
    Qian, H
    Tang, KL
    Liu, CL
    Wang, X
    Gong, QH
    CHEMICAL COMMUNICATIONS, 2002, (06) : 600 - 601
12345