Magnetic field dependence of residual dipolar couplings measured in dilute liquid crystalline media

被引:3
|
作者
Fehér, K [1 ]
Berger, S [1 ]
机构
[1] Univ Leipzig, Inst Analyt Chem, Leipzig, Germany
关键词
residual dipolar coupling; bicelles; magnetic field dependence; fast exchange;
D O I
10.1016/j.jmr.2004.06.014
中图分类号
Q5 [生物化学];
学科分类号
071010 ; 081704 ;
摘要
The effect of the magnetic field strength on the magnitude of residual dipolar couplings introduced by dilute liquid crystal media was investigated. One-bond heteronuclear residual dipolar couplings and residual deuterium quadrupolar splitting of the water were monitored at various static magnetic fields. It is suggested that the value of residual anisotropic NMR parameters resulting from exchange between ordered and non-ordered molecules decreases with increasing magnetic fields. (C) 2004 Elsevier Inc. All rights reserved.
引用
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页码:191 / 198
页数:8
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