Phosphorescent energy relay dye for improved light harvesting response in liquid dye-sensitized solar cells

被引:40
|
作者
Yum, Jun-Ho [1 ]
Baranoff, Etienne [1 ]
Hardin, Brian E. [2 ]
Hoke, Eric T. [2 ]
McGehee, Michael D. [2 ]
Nueesch, Frank [3 ]
Graetzel, Michael [1 ]
Nazeeruddin, Md. Khaja [1 ]
机构
[1] Swiss Fed Inst Technol, Sch Basic Sci, Inst Chem Sci & Engn, Lab Photon & Interfaces, CH-1015 Lausanne, Switzerland
[2] Stanford Univ, Dept Mat Sci & Engn, Stanford, CA 94305 USA
[3] Swiss Fed Labs Mat Testing & Res, Lab Funct Polymers, CH-8600 Dubendorf, Switzerland
关键词
NANOCRYSTALLINE TIO2 FILMS; CONVERSION EFFICIENCY; DOWN-CONVERSION; COMPLEXES; CYANINE; LAYERS;
D O I
10.1039/b925473k
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
Energy transfer from phosphorescent ruthenium complex N877 dissolved in the liquid electrolyte to the squaraine sensitizer SQ1 anchored on the titanium oxide surface resulted in a four fold increase in external quantum efficiency in the blue part of the visible spectrum despite complete quenching of the luminescence of N877 by the iodine in the electrolyte.
引用
收藏
页码:434 / 437
页数:4
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