Functionalization of robust Zr(IV)-based metal-organic framework films via a postsynthetic ligand exchange

被引：105

作者：

Fei, Honghan ^{[1
]}

Pullen, Sonja ^{[2
]}

Wagner, Andreas ^{[2
]}

Ott, Sascha ^{[2
]}

Cohen, Seth M. ^{[1
]}

机构：

[1] Univ Calif San Diego, Dept Chem & Biochem, La Jolla, CA 92093 USA

[2] Uppsala Univ, Dept Chem, Angstrom Labs, S-75120 Uppsala, Sweden

来源：

CHEMICAL COMMUNICATIONS | 2015年 / 51卷 / 01期

基金：

美国国家科学基金会; 瑞典研究理事会;

关键词：

THIN-FILMS; CHEMISTRY;

D O I：

10.1039/c4cc08218d

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

A facile and efficient fabrication approach for homogeneous, crack-free UiO-66 films with exceptionally high crystallinity and tunable thickness on a transparent and conductive glass substrate is reported. Two functionalized species, a catechol ligand and a Fe-2 complex with structural resemblance to the active site of [FeFe] hydrogenase, were introduced into the MOF films via a postsynthetic exchange. Voltammetric studies show the [FeFe] complex in the thinner UiO-66 films (2-5 mu m) can be reduced electrochemically.

引用

页码：66 / 69

页数：4

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