Syntheses with organoboranes -: VIII.: Transformation of (1S,6R)-(+)-2-carene into (1S,6R)-(+)-3(10)-carene and (1R,5R)-(-)-α-thujene into (1R,5R)-(+)-sabinene

被引：5
|
作者：
Zaidlewicz, M [1 ]
Gimiñska, M [1 ]
机构：
[1] Nicholas Copernicus Univ, Fac Chem, PL-87100 Torun, Poland
来源：
TETRAHEDRON-ASYMMETRY | 1997年 / 8卷 / 23期
关键词：
D O I：
10.1016/S0957-4166(97)00589-2
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
The transformation of (1S,6R)-(+)-2-carene and (1R,SR)-(-)-alpha-thujene into (1S,6R)-(+)-3(10)-carene and (1R,SR)-(+)-sabinene, respectively, by metallation-transmetallation-hydrolysis via the corresponding allylic organoborane intermediates is described. (C) 1997 Published by Elsevier Science Ltd. All rights reserved.
引用
收藏
页码：3847 / 3850
页数：4
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