Syntheses with organoboranes -: VIII.: Transformation of (1S,6R)-(+)-2-carene into (1S,6R)-(+)-3(10)-carene and (1R,5R)-(-)-α-thujene into (1R,5R)-(+)-sabinene

被引:5
|
作者
Zaidlewicz, M [1 ]
Gimiñska, M [1 ]
机构
[1] Nicholas Copernicus Univ, Fac Chem, PL-87100 Torun, Poland
关键词
D O I
10.1016/S0957-4166(97)00589-2
中图分类号
O61 [无机化学];
学科分类号
070301 ; 081704 ;
摘要
The transformation of (1S,6R)-(+)-2-carene and (1R,SR)-(-)-alpha-thujene into (1S,6R)-(+)-3(10)-carene and (1R,SR)-(+)-sabinene, respectively, by metallation-transmetallation-hydrolysis via the corresponding allylic organoborane intermediates is described. (C) 1997 Published by Elsevier Science Ltd. All rights reserved.
引用
收藏
页码:3847 / 3850
页数:4
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