Thermolysis specifics of Tin(IV) and Tin(II) complex derivatives:: Thermolysis of (Acac)2SnX2 (X = Cl, N3), (CO)5MSnCl2(thf) (M = Cr, Mo, W), (CO)5MSn(Acac)2, (CO)5MSn(SCN)2, (CH3)4N(CO)5MoSnCl3 (M = Cr, W), and (CO)2MnCpSnCl2(thf)

被引：4

作者：

Dobrokhotova, Zh. B. ^{[1
]}

Koroteev, P. S. ^{[1
]}

Novotortsev, V. M. ^{[1
]}

Egorov, M. P. ^{[1
]}

Nefedov, O. M. ^{[1
]}

机构：

[1] Russian Acad Sci, Kurnakov Inst Gen & Inorgan Chem, Moscow 119991, Russia

来源：

RUSSIAN JOURNAL OF INORGANIC CHEMISTRY | 2007年 / 52卷 / 07期

基金：

俄罗斯基础研究基金会;

关键词：

D O I：

10.1134/S0036023607070200

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Differential scanning calorimetry and thermogravimetry are used to study the thermolysis of following complexes: (Acac)(2)Sn(N-3)Cl (1); (Acac)(2)SnCl2 (2); (CO)(5)MSn(Acac)(2) with M = Cr (3) or W ((4)), (CO)(5)MSnCl2(thf) with M = Cr (5), Mo (6), or W (7)), (CH3)(4)N(CO)(5)MSnCl3 with M = Mo (8) or W ((9)), (CO)(2)MnCpSnCl2(thf) (10)); and (CO)(5)MSn(SCN)(2) with M = Cr (11) or W (12). The phase composition of the solid thermolysis products of compounds 1-5 and 7-12 is determined by X-ray powder diffraction. Thermolysis schemes are suggested.

引用

页码：1109 / 1119

页数：11

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