Dihydrogen trioxide (HOOOH) is generated during the thermal reaction between hydrogen peroxide and ozone

被引：30

作者：

Nyffeler, PT

Boyle, NA

Eltepu, L

Wong, CH

Eschenmoser, A

Lerner, RA

Wentworth, P

机构：

[1] Scripps Res Inst, Dept Chem, La Jolla, CA 92037 USA

[2] Scripps Res Inst, Skaggs Inst Chem Biol, La Jolla, CA 92037 USA

[3] Univ Oxford, Dept Biochem, Oxford Glycobiol Inst, Oxford OX1 3QU, England

[4] ETH Honggerberg, Organ Chem Lab, CH-8093 Zurich, Switzerland

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 2004年 / 43卷 / 35期

关键词：

deuterium; hydrogen peroxide; oxidation; ozone; solid-phase synthesis;

D O I：

10.1002/anie.200460457

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Quantifiable amounts of HOOOH can be detected by 1H NMR spectroscopic analysis; of the thermal reaction of O3 and HOOH (see scheme). This first experimental report of a link between these three oxidants suggests that HOOOH may be involved in oxidation reactions that span biological, atmospheric, and environmental systems.

引用

页码：4656 / 4659

页数：4

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