Dihydrogen trioxide (HOOOH) is generated during the thermal reaction between hydrogen peroxide and ozone

被引：30
|
作者：
Nyffeler, PT
Boyle, NA
Eltepu, L
Wong, CH
Eschenmoser, A
Lerner, RA
Wentworth, P
机构：
[1] Scripps Res Inst, Dept Chem, La Jolla, CA 92037 USA
[2] Scripps Res Inst, Skaggs Inst Chem Biol, La Jolla, CA 92037 USA
[3] Univ Oxford, Dept Biochem, Oxford Glycobiol Inst, Oxford OX1 3QU, England
[4] ETH Honggerberg, Organ Chem Lab, CH-8093 Zurich, Switzerland
来源：
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 2004年 / 43卷 / 35期
关键词：
deuterium; hydrogen peroxide; oxidation; ozone; solid-phase synthesis;
D O I：
10.1002/anie.200460457
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
Quantifiable amounts of HOOOH can be detected by 1H NMR spectroscopic analysis; of the thermal reaction of O3 and HOOH (see scheme). This first experimental report of a link between these three oxidants suggests that HOOOH may be involved in oxidation reactions that span biological, atmospheric, and environmental systems.
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页码：4656 / 4659
页数：4
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