Third-order effect in solid-state NMR of quadrupolar nuclei

被引：29
|
作者：
Gan, ZH [1 ]
Srinivasan, P
Quine, JR
Steuernagel, S
Knott, B
机构：
[1] NHMFL, Tallahassee, FL 32310 USA
[2] Florida State Univ, Dept Math, Tallahassee, FL 32306 USA
[3] Bruker Analyt GmbH, D-76287 Rheinstetten, Germany
来源：
CHEMICAL PHYSICS LETTERS | 2003年 / 367卷 / 1-2期
关键词：
D O I：
10.1016/S0009-2614(02)01681-0
中图分类号：
O64 [物理化学（理论化学）、化学物理学];
学科分类号：
070304 ; 081704 ;
摘要：
The theory and experimental observation of the third-order effect in solid-state NMR of quadrupolar nuclei are presented. The third-order effect consists of spherical harmonic terms up to rank l = 6 and shifts NMR. frequencies between two spin states that are not symmetric such as satellite transitions. Two-dimensional satellite transition magic-angle spinning experiment averages both the first and the second-order quadrupolar interactions making the quantitative measurement of. the third-order effect possible. The third-order quadrupolar effect in andalusite has been measured at 11.7 T and its powder patterns are fitted with numerical simulations. (C) 2002 Elsevier Science B.V. All rights reserved.
引用
收藏
页码：163 / 169
页数：7
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