NON-IDEAL BEHAVIOUR OF BINARY LIQUID MIXTURES AND DIFFERENT APPROACHES TO CALCULATE IDEAL EXPANSIBILITY

被引：4
|
作者：
Kumar, Harsh [1 ]
机构：
[1] Dr BR Ambedkar Natl Inst Technol, Dept Chem, Jalandhar 144011, Punjab, India
来源：
COLLECTION OF CZECHOSLOVAK CHEMICAL COMMUNICATIONS | 2010年 / 75卷 / 02期
关键词：
Binary liquid mixtures; Ideal expansibility; Cyclopentane; 1-Alkanols; Prigogine-Flory-Patterson theory; Thermodynamics; EXCESS MOLAR VOLUMES; 298.15; K; ISENTROPIC COMPRESSIBILITIES; THERMODYNAMIC PROPERTIES; INTERNAL-PRESSURE; WATER MIXTURES; VISCOSITIES; SOUND; 25-DEGREES-C; ACETONITRILE;
D O I：
10.1135/cccc2009503
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
Densities for binary mixtures of cyclopentane with 1-propanol, 1-pentanol, and 1-heptanol over the whole composition range have been measured at temperature 318.15 K. From these densities, excess molar volumes were calculated. All the experimental excess molar volumes were fitted to Redlich-Kister equation and were analyzed with the help of Prigogine-Flory-Patterson theory. Also isobaric expansibilities and their excess counterparts were calculated. Further different approaches were analysed for calculating ideal expansibilities.
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页码：187 / 200
页数：14
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