Growth of KY(WO4)2 single-crystal:: Investigation of the rich WO3 region in the K2O-Y2O3-WO3 ternary system.: 1.: The K2O-WO3 binary system

被引：0
|
作者：
Gallucci, E [1 ]
Goutaudier, C [1 ]
Boulon, G [1 ]
Cohen-Adad, MT [1 ]
机构：
[1] Univ Lyon 1, UMR CNRS 5620, Phys Chim Mat Luminescents Lab, F-69622 Villeurbanne, France
来源：
EUROPEAN JOURNAL OF SOLID STATE AND INORGANIC CHEMISTRY | 1997年 / 34卷 / 10期
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中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
KY(WO4)(2) is known as the most popular third order optically non linear tungstate. Although it is said to be stoichiometric and to melt congruently, single-crystals couldn't be obtained by the Laser Heated Pedestal Growth method. In order to determine the best conditions of crystallization of this compound, the study of its stability domain was undertaken in the ternary system K2O-Y2O3-WO3. This paper reports the first results concerning the K2(O)-WO3 binary system in the composition range between 50 and 100 mol % WO3. Three compounds, K2W3O10, K2W4O13 and K2W6O19 have been underscored and their stability domains have been precised.
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页码：1107 / 1117
页数：11
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