A Mild, Clean, and Simple Synthesis of Symmetrical Carboxylic Anhydrides from Carboxylic Acides Using a Polymer Supported Tosyl Chloride

被引：0

作者：

Zarchi, M. A. Karimi ^{[1
]}

Mirjalili, B. F. ^{[1
]}

Kahrizsangi, Z. Shamsi ^{[1
]}

Tayefi, M. ^{[1
]}

机构：

[1] Yazd Univ, Dept Chem, Yazd, Iran

来源：

JOURNAL OF THE IRANIAN CHEMICAL SOCIETY | 2010年 / 7卷 / 02期

关键词：

Tosyl chloride; Symmetrical anhydrides; Poly(4-vinylpyridine); Acylation; FACILE; AMIDES;

D O I：

暂无

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The use of polymeric reagents simplifies routine acylation of carboxylic acid because it eliminates the traditional purification. We describe the use of readily available cross-linked poly(4-vinylpyridine) supported tosyl chloride, [P4VP].TsCl, in the suspended solution phase synthesis of symmetrical anhydrides from carboxylic acids in the presence of K2CO3 in high yields and purity. The products can be obtained by filtration and evaporation of the solvent.

引用

页码：455 / 460

页数：6

共 45 条

[41] Simple and facile synthesis of aryl benzoates from stabilized arenediazonium tetrafluoroborate using a recyclable polymer-supported benzoate ion
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JOURNAL OF POLYMER RESEARCH, 2012, 19 (11)
[42] Simple and facile synthesis of aryl benzoates from stabilized arenediazonium tetrafluoroborate using a recyclable polymer-supported benzoate ion
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[43] Asymmetric synthesis of 2H-azirines derived from phosphine oxides using solid-supported amines.: Ring opening of azirines with carboxylic acids
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[44] Clean three-step synthesis of 4,5-dihydro-1H-pyrazoles starting from alcohols using polymer supported reagents
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Ley, SV
JOURNAL OF THE CHEMICAL SOCIETY-PERKIN TRANSACTIONS 1, 1998, (15): : 2235 - 2237
[45] Direct synthesis of 2-oxazolines from carboxylic acids using 2-chloro-4,6-dimethoxy-1,3,5-triazine under mild conditions
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TETRAHEDRON LETTERS, 2003, 44 (11) : 2331 - 2333

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