Theoretical investigation of optical and EPR spectra for nickel (II) in ANSH crystal

被引：8
|
作者：
Feng, W. -L. [1 ]
Chen, T. -H. [2 ]
Wang, L. -J [3 ]
Chen, J. -J [2 ]
机构：
[1] Chongqing Inst Technol, Dept Appl Phys, Chongqing 400054, Peoples R China
[2] China W Normal Univ, Dept Phys & Elect Informat, Nanchong 637002, Peoples R China
[3] Neijiang Normal Coll, Dept Phys & Elect Informat Engn, Neijiang 641112, Sichuan, Peoples R China
来源：
OPTIK | 2010年 / 121卷 / 04期
关键词：
Optical properties; Local lattice structure; ANSH crystal; Ni(2+); ELECTRON-PARAMAGNETIC-RESONANCE; LOCAL LATTICE STRUCTURE; IONS; PARAMETERS; HEXAHYDRATE; SULPHATE; V3+;
D O I：
10.1016/j.ijleo.2008.07.015
中图分类号：
O43 [光学];
学科分类号：
070207 ; 0803 ;
摘要：
Based on the semi-self-consistent field (semi-SCF) d-orbital theory and point charge model, we have Studied the optical spectra by the complete diagonalizing (of energy matrix) method (CDM) and electronic paramagnetic resonance (EPR.) spectra by the Perturbation theory method (PTM) for Ni(2+) center in the ammonium nickel(II) Sulfate hexahydrate [(NH(4))(2)Ni(SO(4))center dot 6H(2)O, abbr. ANSH] crystal. The Structural parameters of the ANSH crystal have been obtained and theoretical results agree well with the experimental findings. (C) 2008 Elsevier GmbH. All rights reserved.
引用
收藏
页码：362 / 365
页数：4
相关论文
共 50 条
  • [31] EPR and optical absorption spectra of Mn(II) ions in sodium phosphate glasses
    Chandrasekhar, AV
    Ravikumar, RVSSN
    Reddy, BJ
    Reddy, YP
    Rao, PS
    PHYSICS AND CHEMISTRY OF GLASSES, 2002, 43 (04): : 173 - 175
  • [32] Theoretical Investigation of the Optical Spectra of Organic Compounds in Natural Surrounding
    V. A. Pomogaev
    V. Ya. Artyukhov
    Russian Physics Journal, 2016, 59 : 525 - 535
  • [33] THEORETICAL INVESTIGATION OF THE OPTICAL-SPECTRA OF LIC6
    CHEN, NX
    RABII, S
    PHYSICAL REVIEW B, 1985, 31 (08): : 4784 - 4791
  • [34] EXPERIMENTAL AND THEORETICAL INVESTIGATION OF OPTICAL SPECTRA OF METHYLENE GREEN IN SOLUTIONS
    Tchaikovskaya, O. N.
    Krayukhina, V. S.
    Pomogaev, V. A.
    Chaidonov, A. I.
    RUSSIAN PHYSICS JOURNAL, 2019, 61 (10) : 1752 - 1758
  • [35] Experimental and Theoretical Investigation of Optical Spectra of Methylene Green in Solutions
    O. N. Tchaikovskaya
    V. S. Krayukhina
    V. A. Pomogaev
    A. I. Chaidonov
    Russian Physics Journal, 2019, 61 : 1752 - 1758
  • [36] Theoretical Investigation of the Optical Spectra of Organic Compounds in Natural Surrounding
    Pomogaev, V. A.
    Artyukhov, V. Ya.
    RUSSIAN PHYSICS JOURNAL, 2016, 59 (04) : 525 - 535
  • [37] Synthesis, crystal structure, vibrational spectra, optical properties and theoretical investigation of bis (2-aminobenzimidazolium) tetraiodocadmate
    Kessentini, A.
    Belhouchet, M.
    Sunol, J. J.
    Abid, Y.
    Mhiri, T.
    JOURNAL OF MOLECULAR STRUCTURE, 2013, 1039 : 207 - 213
  • [38] Crystal structures and EPR spectra of Cu2+-doped magnesium(II) and cadmium(II) methoxyacetates
    Hitchman, Michael A.
    Hockless, David C. R.
    Skelton, Brian W.
    Stratemeier, Horst
    White, Allan H.
    ZEITSCHRIFT FUR ANORGANISCHE UND ALLGEMEINE CHEMIE, 2007, 633 (11-12): : 2004 - 2008
  • [39] Optical absorption and EPR spectra of fuchsite
    Reddy, SL
    Reddy, RRS
    Reddy, GS
    Rao, PS
    Reddy, BJ
    SPECTROCHIMICA ACTA PART A-MOLECULAR AND BIOMOLECULAR SPECTROSCOPY, 2003, 59 (11) : 2603 - 2609
  • [40] Optical and EPR spectra of libethenite mineral
    Ferroelectrics, 1-4 (55):
12345