A tetranuclear samarium(ii) inverse sandwich from direct reduction of toluene by a samarium(ii) siloxide

被引：24

作者：

Kelly, Rory P. ^{[1
]}

Toniolo, Davide ^{[1
]}

Tirani, Farzaneh Fadaei ^{[1
]}

Maron, Laurent ^{[2
,3
]}

Mazzanti, Marinella ^{[1
]}

机构：

[1] Ecole Polytech Fed Lausanne, Inst Sci & Ingn Chim, CH-1015 Lausanne, Switzerland

[2] Univ Toulouse, 135 Ave Rangueil, F-31077 Toulouse, France

[3] UPS, CNRS INSA, CNRS, UMR 5215,LPCNO, 135 Ave Rangueil, F-31077 Toulouse, France

来源：

CHEMICAL COMMUNICATIONS | 2018年 / 54卷 / 73期

基金：

瑞士国家科学基金会;

关键词：

LIGAND BENZENE 1,4-DIANION; COMPLEXES; REACTIVITY; LN; METALLOCENES; YTTRIUM; SERIES; STATE; IONS; CP'';

D O I：

10.1039/c8cc04169e

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The dinuclear Sm-II complex, [Sm2L4(dme)] (L = OSi(OtBu)(3)), is easily obtained from the protonolysis reaction of [Sm{N(SiMe3)(2)}(thf)(2)] with HOSi(OtBu)(3). This complex reacts slowly with toluene, resulting in the isolation of the triple-decker arene-bridged Sm-II complex, [{Sm2L3}(2)(-(6):(6)-C7H8)], in 44% yield. This reactivity provides the first example of unambiguous arene reduction by an isolated Sm-II species. In contrast, reduction of [SmL3](2) afforded the inverse sandwich complex, [{KSmL3}(2)(-(6):(6)-C7H8)].

引用

页码：10268 / 10271

页数：4

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