Regioselective Disulfide-Catalyzed Photocatalytic Oxidative Cleavage of 1-Arylbutadienes to Cinnamaldehydes

被引：11

作者：

Fernandes, Rodney A. ^{[1
]}

Kumar, Praveen ^{[1
]}

Bhowmik, Amit ^{[1
]}

Gorve, Dnyaneshwar A. ^{[1
]}

机构：

[1] Indian Inst Technol, Dept Chem, Mumbai 400076, Maharashtra, India

来源：

ORGANIC LETTERS | 2022年 / 24卷 / 19期

关键词：

CARBON BOND-CLEAVAGE; ESSENTIAL OILS; HYDROGEN-PEROXIDE; ESCHERICHIA-COLI; CARBOXYLIC-ACIDS; METAL-FREE; OLEFINS; DERIVATIVES; ALKENES; 1,2-DIOXETANES;

D O I：

10.1021/acs.orglett.2c00884

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

This work discloses a simple, efficient, and environmentally benevolent disulfide-catalyzed photocatalytic regioselective oxidative cleavage of 1-arylbutadienes to cinnamaldehydes. This methodology illustrates mild reaction conditions, ambient temperature, excellent regioselectivity, and compatibility with wide range of functional groups (38 examples). The method gains significance, as few reports with limited substrate scope are available for such excellent photocatalytic oxidative cleavage of conjugated dienes.

引用

页码：3435 / 3439

页数：5

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